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  1. Home
  2. Tungsten Information

Tungsten Copper Sintering Technologies Comparison (1/2)

Category: Tungsten Information
Published on 06 April 2016

There are many kinds of tungsten copper sintering technologies, such as conventional infiltration, mixed-pressing, pressure sintering and new SPS (Spark Plasma Sintering), etc, which have their own advantages and disadvantages. Next, we analyze these different sintering technologies by the principle and the applications. First of all, infiltration, which is called melt immersion, is the most widely used in tungsten copper products currently. It is obtained by adding a small amount of tungsten powder or copper powder compacts made of tungsten powder and tungsten and copper infiltrated compacts stacked together, and thereafter sintered at a temperature above the melting point of copper and under reducing atmosphere or vacuum.

In the process of sintering, copper in a molten state to rely on capillary action infiltrated tungsten skeleton, two sintering and infiltration step can also be performed separately. Infiltration has many advantages, such as high density, excellent sintering properties and electrical and thermal conductivity, good arc ablation resistance. But liquid copper barely rely on capillary forces infiltrated tungsten skeleton, this will lead to coarse and uneven distribution of copper particles sintered tungsten particles at high temperatures easily grew up together. In addition, after infiltration machined to remove excess copper and will increase costs and reduce the yield.

Mixed - pressing sintering process is one of the most conventional powder metallurgy, which basic process is preparation →ball milling → compacting →sintering. Sintering can be also divided into two parts, one is solid phase sintering (temperature lower than the melting point of Cu), the other is liquid phase sintering (temperature higher than the melting point of Cu). Since the solid solubility in the liquid phase W Cu is small, the material can not be conveyed by dissolution and precipitation particles rounded manner, and tungsten and copper infiltration is poor, it is difficult to achieve densification.

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Tungsten Alloy Shielding For Radiation Pasteurization

Category: Tungsten Information
Published on 05 April 2016

Tungsten alloy shielding for radiation pasteurization is used for shielding the radiation released from the process of radiation pasteurization. Radiation pasteurization is a technology that uses ionizing radiation to kill the causative agent (including virus) to achieve the purpose of toxicity elimination. Its radioactive source is Co60 radioactive source which can release γ rays from a decay. The pests and bacteria hided in the fruits and vegetables would suffer from the physiological function changes and lost the ability to grow and develop after being exposed to these γ rays. So far, radiation pasteurization is widely used for the disinfection of various kinds of medical apparatus and instruments, such as catheters, cannulas, bandages, dressings, suture materials, surgical instruments, injection equipments, blood transfusion equipments, artificial kidney dialyzer, biological tissues for transplantation. It also can be used in pharmaceutical, food, agricultural products and customs, etc.

Co60 is a radioactive isotope of cobalt with a half-life of 5.27 years. Co60 decays by beta decay to the isotope nickel-60. The tungsten alloy shielding for radiation pasteurizationactivated nickel nucleus emits two gamma rays with energies of 1.17 and 1.33 MeV. After entering a living mammal, some of the Co60 are taken up by tissues, mainly the liver, kidneys, and bones, where the prolonged exposure to gamma radiation can cause cancer. Low levels of gamma rays cause a stochastic health risk, which for radiation dose assessment is defined as the probability of cancer induction and genetic damage. High doses produce deterministic effects, which is the severity of acute tissue damage that is certain to happen.

Tungsten alloy shielding for radiation pasteurization is mainly used for shielding the β and γ radiation  released from the process of radiation pasteurization. Tungsten alloy shielding mainly uses high gravity alloy which has the characteristics of high density and innocuity. Therefore tungsten alloy shielding for radiation pasteurization has excellent shielding performance to shield  the β and γ radiation  generated during the process of radiation pasteurization, to avoid resulting in radiation damage. In addition, tungsten alloy shielding for radiation pasteurization is more environmentally friendly than some traditional shielding materials, such as lead, and will not pollute the environment. 

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Tungsten Alloy Nuclear Radiation Detector

Category: Tungsten Information
Published on 05 April 2016

tungsten alloy nuclear radiation detectorTungsten alloy nuclear radiation detector, also known as tungsten alloy detecting element, is used to detect nuclear radiation and its properties(including the types, strength ,the energy and nuclear lifetime of nuclear radiation) by utilizing radiation rays to interact with substances to induce a series of effects(such as luminescence phenomenon, ionization effect, physical and chemical changes).It usually made up of a detector, a display unit, a measuring element and a power source, and mainly includes semiconductor detector, gas ionization detector and scintillation detector. Tungsten alloy nuclear radiation detector is widely used in public places, laboratories, quarries, metal processing plants, oil fields and oil pipeline equipment and other departments, for inspection of the radioactivity of underground drill pipe and equipment and building materials, local radiation leakage and contamination and landfill and garbage dump which has the risk of nuclear radiation.

Nuclear radiation, also known as ionization radiation, is a microscopic particle released from the process of a nucleus changes from a structure (or an energy state) to another kind of structure (or another energy state) to cause ionization or excitation material. The types of nuclear radiation include gamma rays, α rays and βrays. Gamma ray is extremely high-frequency electromagnetic radiation and thus consists of high-energy photons. It is penetrating, and can lead to damage at a cellular level, resulting in diffuse damage throughout the body;α rays are generally produced in the process ofα decay. It can enter the body to destroy the human tissues by being inhaled, ingested or injected, αradiation is the most destructive form of ionizing radiation; β rays are able to penetrate living tissues to a certain extent and can change the structure of struck molecules(such as DNA molecules). In most cases, such change can be considered to be damage, with results possibly as severe as cancer or death.

Tungsten alloy nuclear radiation detector uses the tungsten alloy material with high density. Because the radiation shielding capability of a metal material increases with the increasing of its density, so the tungsten alloy nuclear radiation detector has excellent radiation shielding capability. When using a tungsten alloy nuclear radiation detector, the tungsten alloy can absorb and shield the nuclear radiation in a high degree to avoid them doing harm to human body while reaching the goal of nuclear radiation detection.

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Tungsten Alloy γ-Ray Level Gage

Category: Tungsten Information
Published on 05 April 2016

tungsten alloy γ-ray level gageTungsten alloy γ-ray level gage, also known as tungsten alloy γ-ray content gauge or tungsten alloy γ-ray material level meter, is a measuring instrument for mass level by using its characteristic of the strength of rays suffered by detector is various from the levels. It is also an isotope material level meter. Tungsten alloy γ-ray level gage mainly consists of radiation source, detector and transducer. Generally, the radiation source is Co60 or Cs137 radioactive source contained by tungsten alloy container. The function of detector is to detect the rays, and then change the light signals produced by it into electrical signals. While the electrical signals are transformed into contact signals or standard current signals and output to the DOS and other peripheral equipments by transducer. At present, many advanced tungsten alloy γ-ray level gage collectively call detector and transducer as detector.

Tungsten alloy γ-ray level gage has the characteristic of easy operation, simple structure and high measurement accuracy, is particularly useful for measurement of stuff level in harsh conditions(including high pressure, high temperature, high viscosity, high corrosivity, high toxicity and smoke concentration, boiling conditions)or in complicated conditions where general instruments can't or is difficult to use, or for liquid level measurement in the high pressure container which exists liquid drop and liquid surface fluctuation. The material to be measured can be powder, granular solid or liquid. Tungsten alloy γ-ray level gage is mainly used in papermaking, petrochemical engineering, coal industry, mining, steel, thermal power industry, etc. It is only applies to the measurement of two-phase interface.

Due to theγ rays released from theγ-ray level gage can cause DNA and cellular damage, chromosome aberration, chronic and acute radiation sickness, cancer induced. Theγ-ray level gage usually is tungsten alloy γ-ray level gage whose radiation source container is tungsten alloy container. Tungsten alloy γ-ray level gage has high density and great radiation shielding performance, which make it absorb and shield γ rays in a high degree, reducing the harm on human body, to protect the human from the radiation. Moreover, it is environmentally friendly.  

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Typical Recovery Process of Waste WO3 Cellular SCR Denitration Catalyst

Category: Tungsten Information
Published on 05 April 2016
Theoretically, SCR denitration catalyst has unlimited life, but it’s life limited by various reasons; at the same time, under the collective effect of the economy and market, the catalyst has shorter and shorter life, and a large amount of waste tungsten trioxide denitration catalysts are produced. For the continually produced waste catalysts, the best way to treat is resources renewable (the regeneration frequency can only reach 2~3 times); followed by is recycling to ensure maximum utilization of resources, thus realize the goal of saving resources, protecting the environment; and the worst treatment way is landfill with harmless.

cellular SCR denitration catalyst
 
The steps of typical recovery processing of waste honeycomb SCR catalyst are as follows:
1. SCR spent catalyst was carried out pretreatment like washing, removing ash, then wet grinding, leaching under high temperature and pressure;
2. Adding hydrochloric acid into the leach solution to adjust pH value and remove impurities;
3. Adding hydrochloric acid into leach residue, calcining after fully react to prepare titanium dioxide or titanium-rich material;
4. Preparation of ammonium paratungstate;
5. Preparation of vanadium pentoxide;
6. wastewater reuse treatment.
 
The main products of this process have properties like high purity and recovery rate, mainly as follows: the content of titanium dioxide in rutile titanium dioxide is up to about 90%, and the recovery rate of titanium dioxide is nearly 90%; the content of tungsten trioxide in ammonium paratungstate can be higher than 99%, the recovery rate of tungsten oxide maybe higher than 80%; the content of vanadium pentoxide can reach to 93%, and the recovery rate is higher than 60%.
 
Also the compound with Na and Cl elements introduced can get recycled, the recycling cost of raw material can be lower.
 
In addition, there is no emission of secondary pollutants, mainly performance as follows: the using of washing ash with high-pressure-water and the washed water reused; crushing, fine grinding and leaching when the material is wet; the side-products can be directly sold; wastewater spray for absorbing calcination exhaust.
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WO3 SCR Waste Denitration Catalyst Recovery Process

Category: Tungsten Information
Published on 05 April 2016
There are four processes for recycling waste tungsten trioxide SCR denitration catalyst as following:
1. The waste tungsten trioxide SCR denitration catalyst was crushed and re-added to the new manufacturing process of catalyst. In this process, the amount of recovery catalyst is limited, thus the goal of recycling all the waste catalyst can’t be realized.
2. The material carried out sodium treatment and roasting→precipitate V by ammonium chloride from the leachate→ precipitate tungsten by calcium chloride→ de-integrating the Na4TiO4 by sulfuric acid; or sodium treatment and roasting→ precipitate tungsten by calcium chloride→ realize the separation of tungsten and V by forming ammonium paratungstate.
Such technology has the following properties:
(1) The material should be crushed before roasting, and always require the particle size equals to or less than 200μm, otherwise it will cause a serious loss of fly ash and large amounts of carbon dioxide emissions in the calcination process;
(2) The heat cannot get fully used;
(3)The separation step and impurity removal method of waste tungsten trioxide denitration catalyst isn’t well considered, and cause the purity of recovered products limited;
(4) does not form a good cycle of process wastewater reuse.

steel SCR denitration catalyst

3. Two times of electrolysis with strong electrolyte solution→ adjust pH with ammonium to precipitate vanadium. The industrial application and energy consumption of this process is unknown; besides, W, Ti and other components cannot be separated for recycling.
4. The pretreatment of removing ash→ alkaline leaching at high temperature and pressure→ removing impurities with magnesium salts→ precipitate tungsten and vanadium with calcium salts→ de-integrating the tungsten, vanadium and calcium salts→ extract vanadium→ prepare the material which is rich in titanium→ wastewater reuse treatment. This is the better treatment processing with purity of the recovered products well controlled; moreover, elements Na and Cl well recycling and the energy get fully used.
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Shape Influence on CsxWO3 Nanocrystals Surface Plasmon Resonance

Category: Tungsten Information
Published on 05 April 2016

Surface plasmons (SPs) are coherent delocalized electron oscillations that exist at the interface between any two materials where the real part of the dielectric function changes sign across the interface (e.g. a metal-dielectric interface, such as a metal sheet in air). SPs have lower energy than bulk (or volume) plasmons which quantise the longitudinal electron oscillations about positive ion cores within the bulk of an electron gas (or plasma). The charge motion in a surface plasmon always creates electromagnetic fields outside (as well as inside) the metal. The total excitation, including both the charge motion and associated electromagnetic field, is called either a surface plasmon polariton at a planar interface, or a localized surface plasmon for the closed surface of a small particle. The existence of surface plasmons was first predicted in 1957 by Rufus Ritchie. In the following two decades, surface plasmons were extensively studied by many scientists, the foremost of whom were T. Turbadar in the 1950s and 1960s, and Heinz Raether, E. Kretschmann, and A. Otto in the 1960s and 1970s. Information transfer in nanoscale structures, similar to photonics, by means of surface plasmons, is referred to as plasmonics.

Localized surface plasmon resonance phenomena have recently been investigated in unconventional plasmonic materials such as metal oxide and chalcogenide semiconductors doped with high concentrations of free carriers. Synthesize colloidal nanocrystals of CsxWO3, a tungsten bronze in which electronic charge carriers are introduced by interstitial doping. By using varying ratios of oleylamine to oleic acid, synthesize three distinct shapes of these nanocrystals—hexagonal prisms, truncated cubes, and pseudospheres—which exhibit strongly shape-dependent absorption features in the near-infrared region. It's rationalized these differences by noting that lower symmetry shapes correlate with sharper plasmon resonance features and more distinct resonance peaks. The plasmon peak positions also shift systematically with size and with the dielectric constant of the surrounding media, reminiscent of typical properties of plasmonic metal nanoparticles.

absorbance

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CsxWO3 Hydrothermal Synthesis and Near-Infrared Shielding Properties

Category: Tungsten Information
Published on 05 April 2016
Cesium tungsten bronze (CsxWO3, x=-0.1、0.2、0.3) powders were synthesized with different cesium content by the low temperature hydrothermal method in citric acid solution. Citric acid is a weak organic tribasic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in the metabolism of all aerobic organisms. More than a million tons of citric acid are manufactured every year. It is used widely as an acidifier, as a flavoring, and as a chelating agent. A citrate is a derivative of citric acid; that is, the salts, esters, and the polyatomic anion found in solution. An example of the former, a salt is trisodium citrate; an ester is triethyl citrate. When part of a salt, the formula of the citrate ion is written as C6H5O73− or C3H5O(COO)33−.
 
Hydrothermal synthesis includes the various techniques of crystallizing substances from high-temperature aqueous solutions at high vapor pressures; also termed "hydrothermal method". Temperature-difference method is the most extensively used method in hydrothermal synthesis and crystal growing. Supersaturation is achieved by reducing the temperature in the crystal growth zone. The nutrient is placed in the lower part of the autoclave filled with a specific amount of solvent. The autoclave is heated in order to create two temperature zones. The nutrient dissolves in the hotter zone and the saturated aqueous solution in the lower part is transported to the upper part by convective motion of the solution. The cooler and denser solution in the upper part of the autoclave descends while the counterflow of solution ascends. The solution becomes supersaturated in the upper part as the result of the reduction in temperature and crystallization sets in.
 
The CsxWO3 film was prepared with PVA as film forming agent by roller coating method. The near-infrared shielding and heat insulation performance of the glass coated with CsxWO3 film with different cesium content were mainly investigated. The results indicate that the near-infrared shielding and insulation of the glass coated with CsxWO3 film is improved with the increasing of the cesium content. By comparison with the blank glass, the glass coated with Cs0.3WO3 film has best near-infrared shielding and heat insulation, and the temperature difference of heat insulation can attain to 13.5℃.

Heat insulation curve of glass coated with CsxWO3 film
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Cerium-Tungsten Trioxide SCR Denitration Catalyst 2/2

Category: Tungsten Information
Published on 01 April 2016
Rare earth element - tungsten trioxide SCR denitration catalyst can be applied to coal-fired power, glass, cement, steel mills plants, heating boiler room and other coal, oil, SCR flue gas denitration process. At the same time, because of this tungsten trioxide SCR catalyst belongs to rare earth system, which has many excellent properties, such as non-toxic, no need to recover, no fear for water, can be regenerated for several times, also it can be made into honeycomb, plate and corrugated and other types. This type of SCR denitration catalyst maybe possible fully replaces the imported VW-Ti system SCR catalyst technology in the near future.

tungsten vanadium rare earth based powder
 
Compares to ordinary V-W-Ti system catalyst, this cerium rare earth element tungsten trioxide denitration catalyst has many advantages:
1. None toxic effects, do not cause harm to humans and the environment;
2. Efficiency with long life
Experiments show that the catalytic ability of rare earth elements is higher than vanadium (V) element, thus brings the titanium dioxide, tungsten trioxide and other components reduced, so that the production costs reduced at the same time. Meanwhile, the increasing content of alumina also bring catalyst stiffness and hardness markedly improved, thus make the catalyst has longer life and better suit for glass furnace, cement, coal boiler other severer operating conditions with high ash content in flue gas;
3.Temperature window broaden, the minimum working temperature of this rare earth cerium-tungsten trioxide SCR denitration catalyst is as low as 260℃, which is 50℃ lower than the average 310℃, making the use scope expanded;
4. Can be regeneration more times, this kind of rare earth element catalyst is able to withstand repeated washing without damaged which means higher regeneration ability, it also greatly reducing the cost and realizing the goal of economic interests.
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Cerium-Tungsten Trioxide SCR Denitration Catalyst 1/2

Category: Tungsten Information
Published on 01 April 2016
CeFrom the precious metal catalyst to today widely used SCR denitration catalyst which is using titanium dioxide as the main catalyst carrier, vanadium pentoxide, tungsten trioxide as main active ingredient, the SCR denitration catalyst has experienced a variety of important technological changes and condensed years of hard work from academics and numbers of plant personnel.
 
However, since the vanadium itself is highly toxic, it’s easy to cause body bronchitis, impaired vision and kidney damage. If the waste catalysts are not recovered, they will do a huge damage to environmental and body, therefore, in the great situation of environmental protection, the user must spend an expensive special costs in the recycling of waste SCR denitration catalyst. Faced with this situation, promoting a new non-toxic catalyst product has become the focus supporting and developing projects for government.
 
Many scholars and manufacturers have made great efforts in this area, also there is a new type of highly efficient, inexpensive SCR denitration catalyst product has been successfully developed. This non-toxic SCR denitration catalyst takes modified rare earth functional ceramics as a carrier, and takes cerium dioxide, tungsten trioxide as the main active ingredients; also it is mixed with a certain amount of zirconium dioxide, glass fibers, and other trace components.
 
Cerium, a silver-gray active metal, its powder is easily spontaneous combustion in the air, can soluble in acid, the highest abundance of rare earth elements. Cerium is easily oxidized at room temperature; therefore, when exposed in the air, it is easy to lose its luster and can even burn by using a knife to rasp in the air. Cerium is mainly as a reducing agent in the catalyst; it can be used as additives in manufacturing cerium salts for manufacturing medicine, leather, special glass, textile and other industries; at the same time, cerium alloy can be used to manufacture jet propulsion components because of its heat-resistant.
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