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  1. Home
  2. Tungsten Information

Tungsten Copper Contact HIP Process (1/2)

Category: Tungsten Information
Published on 08 April 2016

Tungsten copper contact has excellent electrical, thermal conductivity and chemical stability, but the problem in densification is always a barrier in its developing way. And this incomplete densification will have an bad influence on the hardness, the strength, wear resistance and arc ablation resistance conversely. So the relevant researchers propose that pressure sintering, a total reduction of chemical and explosive compaction method special process to improve the density of tungsten copper contact material. However, there are some defects in these processes, such as high operation and maintenance costs, be suitable for the parts with small size and so on.

In order to improve the properties of tungsten copper contacts, we combine tungsten copper contact used in high voltage circuit breakers to study HIP process for tungsten copper material impact, and its elimination of the porosity, densification mechanism and related factors. HIP (Hot Isostatic Pressing), it places the product into a closed container, which is applied to each peer pressure while applying heat, under the action of high temperature and pressure, the product can be sintered and densified. HIP has many advantages, such as combines the advantages of hot pressing with isostatic pressing, lower molding temperature, excellent densification and performance, which is essential for high-performance material manufacturing; now, in the United States, Japan and Europe to achieve the industrial, marine, aviation, aerospace, automotive and other fields have been widely used.

tungsten copper contact

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Wet Chemical Method of Tungsten Bronze Preparation

Category: Tungsten Information
Published on 08 April 2016
Hydrothermal synthesis is the most important method in the wet chemical method, it was introduced to the process of tungsten bronze preparation in the early 1980s. Mix WO3-W-LiOH as ratio of 1: 3: 2 in a certain amount of water, heated under 700 ℃ (constant pressure) for 9h to prepare purple crystal, proven as the hexagonal structure Li0.30WO3 with a = 0.740 5 nm and c = 0.755 4 nm. The early hydrothermal synthesis temperature is relatively high, and now it is reported that more low-temperature hydrothermal synthesis.
 
Kenneth P. Reis and A. Ramanan prepared tungsten bronze hexagonal structure by hydrothermal synthesis by acidified tungstate solution. Reaction in solution at T = 155 ℃, P = 5kPa for about 3 d, the control of pH value of duration is critical. The product synthesis unit cell parameters are a = 0.730 0 nm, c = 0.771 9 nm of hexahedral LixWO3 + x / 2. Similar low-temperature hydrothermal synthesis, that several reactions in aqueous solution is directly heated, there are more reports about pressurized synthesis tungsten bronze crystals. As WO3, KOH and N2H4·H20 react at 360 ℃, prepare single crystal whiskers of K0.4WO3. Acidify WO3, NaBH4 (or KBH4) with hydrochloric acid, prepare NaxWO3 (or KxWO3) sol at 350 ℃, and annealing by 600 ℃ and 850 ℃  to obtain crystals. Hydrothermal synthesis at low temperatures must solve the problem of the intensity of reducing selection, in order to ensure the portion W6 + reduction, thereby generating tungsten bronze. Select acidification and use of organic synthesis are commonly-used means of strong reducing agent.
 
In wet chemical method, because of its relatively low synthesis temperature, the better product crystallized state becomes a hot research focus of synthesis method, but there are not many tungsten bronze kinds now synthesized by this method .

tungsten bronze
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Tungsten Alloy Shielding For Digital Compound Machine

Category: Tungsten Information
Published on 07 April 2016

Tungsten alloy shielding for digital compound machine is used to shield the radiation released from the digital compound machine. Digital compound machine, also known as copying machine, is the ultimate tool for the modern office. It is a machine that outputs document in the form of laser printing and can edit and operate images and text as required. In addition to the basic function of copying, it also can be used for printing, scanning, fax, etc. Digital compound machine is to translate the optical signals of original manuscript scanned by the optical system into electrical signals by CCD, then process the image signal through digital image processing circuit and input them into the laser modulator. Modulated laser beam will scan photosensitive drum which is charged to produce electrostatic effect, and complete the copying process after developing, transfer printing and fixing. Digital compound machine substantially has the same functions with laser printer and scanners.

tungsten alloy shielding for digital compound machineThe form of laser printing used by digital compound machine is an electrostatic digital printing process. It produces high-quality text and graphics by repeatedly passing a laser beam back and forth over a negatively charged cylinder called a "drum" to define a differentially-charged image. The drum then selectively collects electrically charged powdered ink, and transfers the image to paper, which is then heated in order to permanently fuse the text or imagery. Today, it is accepted that even low-power lasers with only a few milliwatts of output power can be hazardous to human eyesight when the beam hits the eye directly since the laser has thermal effect, light pressure effect, electromagnetic effect and biostimulation. And laser radiation can also cause skin burns with difficulty heals, skin aging. What's more, the electromagnetic radiation released from digital compound machine also easy to cause fetal malformation, miscarriage, premature birth. Therefore, it is better to put a tungsten alloy shielding around the digital compound machine to shield the radiation generated from it.

Tungsten alloy is a tungsten-base alloy with addition of some other elements. According to the research, the radiation shielding performance of a metal material increases with the enhancing of its density, the density of tungsten alloy can reach very high, and therefore it has great radiation shielding ability to effectively absorb and shield radiation released from the digital compound machine, so as avoiding these radiation damaging office workers. With the popularity of digital compound machine in major offices, tungsten alloy radiation shielding for digital compound machine will also serve as a radiation shielding appearing in major offices. 

Tungsten Alloy Supplier: Chinatungsten Online www.tungsten-alloy.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Tungsten Alloy Radiopharmaceuticals Container

Category: Tungsten Information
Published on 07 April 2016

tungsten alloy radiopharmaceuticals containerTungsten alloy radiopharmaceuticals container is used for containing radiopharmaceuticals which have radioactivity. Radiopharmaceuticals are a group of pharmaceutical drugs or biological agents which have radioactive nuclides. Radiopharmaceuticals can be divided into diagnostic radiopharmaceuticals and therapeutic radiopharmaceuticals, which used for medical diagnosis and treatment, respectively. Diagnostic radiopharmaceuticals mainly include compounds labeled by 99mTc, 201TI, 67Ga, 123I, 75Se, 51Cr and 113mIn whose location and variations in vivo can be detected by γ-ray detector in vitro; while the therapeutic radiopharmaceuticals are compounds labeled by 131I, 32P, 198Au, 186Re, 89Sr, 90Y, 153Sm, 188Re, 117mSn, 117Lu, which achieve the desired therapeutic effect by providing focused radiation exposure to the diseased tissue of a patient. 131I is still the most commonly used radiopharmaceuticals for treatment of thyroid disease.

With the development of nuclear technology in the medical field and the emergence of Nuclear Medicine, the demand for radiopharmaceuticals is also increased significantly. In addition to be used for diagnosis and treatment of thyroid diseases, radiopharmaceuticals are also used for a variety of imaging such as gastric imaging, brain imaging, adrenal imaging, myocardial imaging, liver imaging, heart and great vessels blood pool imaging, and for renal function tests, pulmonary function tests, lung tumor diagnosis, localization of placenta, measurement of red blood cell life span, malignant effusion control, treatment of polycythemia vera and skin disease. Because radionuclides contained in radiopharmaceuticals can emit α rays, β-rays, γ-rays and other rays which have radioactivity, causing harm to human body. Therefore, it is necessary to use a tungsten alloy container for storing radiopharmaceuticals to prevent them from entering into the human body to cause internal exposure by all kinds of ways.

Tungsten alloy radiopharmaceuticals container with great radiation shielding effectiveness can shield radiation generated by radiopharmaceuticals, or prevent them from entering into the human body, to protect staffs and patients from radiation damage. Compared with traditional materials (such as lead), tungsten alloy has a higher density, so as in the case of equal quality, the volume of tungsten alloy is only 1/3 of lead, while the radiation shielding performance is not diminished. And tungsten alloy will not pollute the environment due to its environmental protection feature. 

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Tungsten Alloy Microwave Dryer

Category: Tungsten Information
Published on 07 April 2016

tungsten alloy microwave dryerTungsten alloy microwave dryer is a new kind of equipment to dry materials by use of microwave technique. Its working principle is acting on the molecular motion. When drying materials, microwave acts directly on the molecule and is converted into thermal energy. Due to the absorbency and penetrability of microwave, water and food can absorb microwave to make themselves heat. Moreover, the uniformity and conformity of heating process prompt the rate of heating to be fast and improve the drying quality greatly.In a word, tungsten alloy microwave dryer has the advantages of quick drying, uniform drying, energy efficient, clean production, easy to automate control and improving product quality.

Tungsten alloy microwave dryer is widely used in food industry, ceramic industry, pharmaceutical industry, chemical materials, laboratory analysis. Such as the drying of powder, grain, slice, strip, plate, small blank, high moisture sticky materials and other materials; activation and regeneration of the catalyst; drying, sterilization and disinfection of sludge and other solid waste and food, medicine, pharmaceutical raw materials;drying, deinsectization and mould proof of rice, flour; solidification of high polymer material. Microwaves are a form of electromagnetic wave with wavelengths ranging from one meter to one millimeter. Long-term exposure to microwave radiation can produce heat damage in human tissues, up to and including serious burns that may not be immediately evident because of the tendency for microwaves to heat deeper tissues with higher moisture content, and will cause neurasthenia, weakened immunity, hemodynamic disorder and other affects. 

It is inevitable to be affected by electromagnetic radiation during the drying process, and induce radiation damage over time. The best solution is tungsten alloy microwave dryer. Tungsten alloy microwave dryer is made up of tungsten alloy material with high density, and thus has good radiation shielding properties, which can efficiently absorb and shield radiation. Therefore, tungsten alloy microwave dryer is capable of shielding microwave radiation, to prevent leakage of microwave radiation, then protect human body from radiation injury. 

Tungsten Alloy Supplier: Chinatungsten Online www.tungsten-alloy.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Working Condition Affects Tungsten Trioxide SCR Denitration Catalyst 2/2

Category: Tungsten Information
Published on 07 April 2016
4. High content of sulfur
High content of sulfur usually occurs when burning coal with high-sulfur content, the increasing of sulfur dioxide in flue gas means the more sulfur trioxide; sulfur trioxide can react with the reducing agent--ammonia and generate a large amount of ammonium bisulfate and ammonium sulfate. Ammonium bisulfate is an extremely viscous substance which is very difficult to be removed when adhering to the SCR device; at the same time, the ammonium bisulfate adhering to the surface of tungsten trioxide SCR denitration catalyst, it will continue adsorb fly ash and  resulting catalyst blocking. Ammonium sulfate is a dry powdery substance, when in the case of large amounts of fly ash in the flue gas, both the worn out and blocking of catalyst will be increased.

coal plant SCR denitration
 
5. Waste incineration, co-firing biomass fuel
Waste incineration power generation and co-firing sewage sludge are the good solutions for solving environmental pollution and energy crisis, but they also put forward higher requirements in the designing, operating of tungsten trioxide SCR denitration catalyst. This is because the content of P, Na, K, CaO is likely ten times the number of ordinary coal, all these elements can cause catalyst poisoning. Due to the strong toxicity of alternative fuels, they will cause great harm to the tungsten trioxide SCR denitration catalyst even though burned in a very short time. Since Chinese have very low environmental awareness, the situation of classifying strictly in widespread municipal solid waste, industrial waste, municipal and industrial sludges is so poor, which causes the smoke and ash content of the alternative fuels complex and can’t clearly distinguish; besides, the many more unknown poisons greatly limit the chemical life assessment and economic analysis of the catalyst.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Working Condition Affects Tungsten Trioxide SCR Denitration Catalyst 1/2

Category: Tungsten Information
Published on 07 April 2016
The properties of tungsten trioxide SCR denitration catalyst will cause a direct effect on the whole denitration system, the different working conditions cause the different catalyst design; therefore, the scientific and reasonable choice of a catalyst form, amount and type is becoming the key of designing SCR denitration system. In this paper, we propose how the five kinds of working conditions affect tungsten trioxide SCR denitration catalyst.

SCR denitration catalyst
 
1. High content of calcium
CaO will cause catalyst poisoning, it performance as that when the content of CaO is very high in the fly ash, or the flue gas has a high sulfur trioxide content, large amounts of calcium sulfate will easy to produce in the catalyst surface, they adhere to each other thus to form a bridge, and cause shielding of catalyst surface, thereby reducing catalyst activity.
 
2. High ash
Currently, the mainstream types of catalyst have been used are honeycomb, plate and corrugated plate. Among them, the plate exhibits more favorable advantage in a high fly ash condition; and corrugated plate shares a relatively low market, which is less than 5%. Generally, when the concentration of fly ash in flue gas is among 50~60g/Nm3 or even higher, choosing the plate which is not easy to plug fouling will bring more safety operation, due to the far greater cross-sectional area it has. However, when in a lower ash concentration, the plate catalyst will inquire 20%~40% more than the honeycomb under the same engineering conditions, thus resulting in initial purchase costs of the catalyst and other auxiliary parts increasing.
 
3. High temperature
The suitable temperature of tungsten trioxide SCR denitration catalyst is generally 300~400°C, however, even in this temperature range, a large amount of catalyst will be required to meet the basic denitration ratio. The amount of catalyst depends on the parameter like NOx concentration, gas flow, and denitration efficiency requirements.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Arc Performance Affected By Tungsten Electrode Organizational Structure

Category: Tungsten Information
Published on 07 April 2016

tungsten electrods

During the welding process, arc performance not only connects with power supply unit and the environmental conditions, it also depends largely on the tungsten electrode’s arc performance. Good arc performance directly determines the use and application range of tungsten electrodes. The organizational structure of the tungsten electrode has a certain impact on tungsten electrode’s arc performance. In general, the integrity and uniformity of the tungsten electrode structure will directly affect the arc performance. If tungsten electrodes inside has splitting, delamination, micro-cracks, voids, mezzanine or severe non-uniform grain structure, the arc process is instability. So it will occur arc breaking, arc blasting, drift, and the worst case will cause thermal and electric, conductivity decreased, so that electrode’s local will overheating, melting, deformation, reducing the arc performance. In addition, at high temperatures, the electrode structure is closely related to the chemical composition. At High temperature, the doped rare earth oxides is easily migration, evaporation, dilution resulting in recrystallization coarsening to cause cracks.

Organizational structure and chemical composition of the tungsten electrode can affect their physical and mechanical properties, thus affecting its arc performance. Tungsten electrode as an important part in welding tool should have good physical and mechanical properties, such as, high melting point, high boiling point, low vapor pressure, good thermal conductivity and electrical conductivity, high temperature strength and high recrystallization temperature and creep and other good properties. If the physical property and mechanical properties of the tungsten electrode is defective, then it can result in electrode deformation and melting during the welding, leading arc performance deterioration. Different type rare earth tungsten electrodes have different deformation resistance and high temperature resistance. In general, tungsten electrode doped with two rare earth oxides is better than pure tungsten electrode and tungsten electrode doped with three rare earth oxides is better than tungsten electrode doped with two rare earth oxides.

Tungsten Metals Supplier: Chinatungsten Online www.tungsten.com.cn Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Arc Performance Affected By Tungsten Electrode Chemical Composition

Category: Tungsten Information
Published on 07 April 2016

thorium tungsten electrodes

Tungsten electrode arc performance is affected by physical and chemical property, mechanical properties, chemical composition and organizational structure. The following will analyzes the influence of tungsten electrode chemical composition on arc performance in welding process.

Pure tungsten electrode has high electron work function and it is not conducive to high electron stream emission, so the service life and arc performance is poor, which directly affect the welding performance. In order to improve the disadvantages of pure tungsten electrode, with further research, manufacturers developed rare earth tungsten electrode and multiple rare earth tungsten electrodes. According to the current density formula of physics emission mechanism Je = AT2exp (-eφ / kT) shows that, in order to reduce eφ (electronic charge), we can add rare earth oxides or other elements in tungsten electrodes to low eφ’s value. Different types of rare earth tungsten electrodes having a particular Je value, so they arc performance are relatively stable.

Tungsten electrodes chemical composition’s type, content, distribution and high temperature characteristics determine the ignition and stability of the arc. In terms of content, taking single rare earth doped tungsten electrode as example, rare earth oxide content is higher, the better the arc performance of the electrodes. In addition, the uniformity distribution and high temperature evaporation and diffusion behavior of rare earth oxides also affected arc performance to some extent. The main reason for arc performance deterioration is caused by doped rare earth’s evaporation and decomposition. Different type rare earth tungsten electrode under different conditions has difference arc performance, tungsten electrode doped with two rare earth oxides is better than pure tungsten electrode and tungsten electrode doped with three rare earth oxides is better than tungsten electrode doped with two rare earth oxides.

Tungsten electrode during operation, the ends of the electrodes will produce ring mushroom nodules, called "Rim" phenomenon. This is because tungsten electrode surface has more added rare earth oxide content than the central portion, in favor of arc in a short time. When the protective gas is mixed with a small amount of O2 or welding parameters transferred to short-term overload state, it will occurs "Rim" phenomenon. This phenomenon is still under study, some scholars believe that this is due to the tungsten oxide and rare earth oxides evaporation, decomposition, precipitation and segregation at the high temperature to occur dephlegmation and segregation precipitation. In fact, it is the chemical composition of the tungsten electrode changed at high temperatures. "Rim" phenomenon is good for arc in short time, but for a long time will lead to surface additives concentration reduction affected arc electrode performance and increased consumption.

Tungsten Metals Supplier: Chinatungsten Online www.tungsten.com.cn  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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TiC Effect on Tungsten Carbide Button Properties (2/2)

Category: Tungsten Information
Published on 07 April 2016

With the increase of the added amount of TiC, its grain refinement, solid solution strengthening effect began to appear, which is beneficial for improving the bending strength of tungsten carbide buttons. And thereafter continue to add TiC, sintered body appeared in the ring structure with non-normal tissue, which is thus the core parts containing lower amounts of solid solution WC and an outer layer containing a high amount of WC solid solution consisting of the ring with will make the structure appear flexural strength decreased more obviously. The variation of fracture toughness is similar to the bending strength.

From the point of view fracture surface, tungsten carbide button after fracture section added TiC is smoother and the distribution is more uniform. And by observing the hard phase of WC and Co binder phase section can be found in WC grains tend to diversify, it also shows that the fracture of the alloy phase is broken along the border and the bonded phase WC grains and binder phase, rarely WC grains through the break, and it is related to the dispersion of fine-grained solid solution with TiC phase of strengthening.

Furthermore, there are some pores in the section, especially the surface of alloy without adding TiC. In the process of solid phase sintering, because of rigid WC skeleton hinder shrinkage during cooling of briquettes contraction and solidification Co generated carbide makes it impossible to completely fill the screen, resulting in the formation of pores shrink tube; on the other hand, uneven distribution and the gas generated during sintering forming agent is one of the reasons. In addition, TiC also has an influence on the routes of cracks expanding. It will have containing and pinning effect on the movements of WC grain boundaries. And owing to a great difference of elastic modulus and coefficient of thermal expansion, the residual stress of TiC and the matrix in the process of sinter cooling, which resulting in cracks in the offset process of moving forward, extending the cracks propagation path.

Tungsten Carbide Supplier: Chinatungsten Online tungsten-carbide.com.cn Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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