☰

中钨在线新闻网

  • Home
  • Tungsten News
    • Tungsten's News
    • Tungsten Information
    • Tungsten Statistics Data
    • Tungsten Patents
    • Tungsten Dart News
    • Rare Earth News
    • Tungsten Jewelry News
    • Sapphire Growth Furnace
    • Smart Glass
  • Tungsten Video
  • Tungsten Audio
  • Tungsten Price
    • Tungsten Metal Price
    • Tungsten Electrodes Price
    • Tungsten Alloy Price
    • Tungsten Military Parts Price
    • Tungsten Carbide Price
    • Tungsten Powder Price
    • Tungsten Carbide Powder Price
    • Tungsten Oxide/Trioxide Price
    • Ammonium Metatungstate
    • Tungsten Concentrate Price
    • Ferro Tungsten Price
    • Tungsten Jewelry Price
    • Gold Plated Tungsten Price
    • Tungsten Dart Price
    • Tungsten Fishing Sinkers Price
    • Tungsten Copper Price
    • Tungsten Bucking Bar Price
    • Sapphire Growth Furnace Price
  • About Us
    • About Us
    • Contact Us
    • Visit Us
  • Disclaimer
    • Terms & Conditions
    • Agent
    • Privacy Policies
    • Intellectual Property
    • Recycle Policy
    • Disclaimer
    • Statement
  • Language
    • 繁體中文
    • 繁體中文
    • 日本語
  • 简体中文
  1. Home
  2. Tungsten Information

Commercial Recovering Value of Waste WO3 Denitration Catalyst

Category: Tungsten Information
Published on 14 April 2016
valuable metal content in waste denitration catalystThere are a large number of valuable metals in the waste SCR denitration catalyst, if directly discarded, it will cause a huge resources waste; furthermore, vanadium pentoxide can cause environmental pollution because of its highly toxic. For reducing environmental pollution caused in denitration catalyst regeneration process, to establish a program for generating material with high content of valuable metals, and its products can be sold directly as a raw material thus to have some commercial value.
 
The detailed description plan is showed as below:
1. Calcining the waste tungsten trioxide denitration catalyst at 800~850 ℃ for 7 ~ 8 hours, for making the material of titanium, tungsten, vanadium, molybdenum oxidized sufficiently, and removing spent catalyst and combustibles volatile at the same time; cooled after released, and then pulverized to 60 mesh or less for inactive using;
2. Leaching out the material with ammonia which has been calcined and ground at 80~90℃ for 7 to 9 hours, until the mass of tungsten trioxide and molybdenum trioxide are all leached out; carrying out filtration to separate the leaching solution containing tungsten along with molybdenum and leach residue containing titanium vanadium;
3. The leachate is first carried out Mo precipitation with ammonium sulfide, taken out filtration after Mo completely precipitated thus to get the molybdenum sulfide which can be sold as raw molybdenum material; besides, the ammonium tungstate is remained in the filtrate solution;
4. Concentrate the filtrate to about 45% of its original volume by evaporation, and then adjust the pH value to 6.2 with nitric acid, while reducing the temperature of the solution to about 15℃at the same time, and incubated for 5 hours to precipitate ammonium paratungstate crystals, then directly packing the APT for selling after washed, and the crystal liquor returns to evaporation process;
5. Leaching out the vanadium in the residue by reduction roasting method, by the way titanium leaves in the leaching residue, thus to separate vanadium and titanium; after cooling down and filtrating, the residue can be sold as the titanium-rich material;
6. Add KClO3 into the filtrate to precipitate V2O5, and it can be sold as vanadium application raw material, and the potassium mother liquor can be used as an agricultural fertilizer.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

What is JEOL EB Tungsten Filament?

Category: Tungsten Information
Published on 14 April 2016

The full name of JEOL is Japanese Electron Optics Laboratory. After decades of exploration and research by the world’s top scientific instrument manufacturers, they create the brand JEOL. Nowadays, JEOL products are widely applied in the fields of medicine, biology, biochemistry, agriculture, material science, metallurgy, chemical, petroleum, pharmaceuticals, semiconductor and electronics. EB (electron beam) tungsten filament of JEOL is known to the Chinese businessmen. So far, there are more than 2000 users of JEOL in China. In China, EB tungsten filament of JEOL is used by a key laboratory sciences sector, research institutes, universities, medical institutions, government agencies and enterprises.

EB tungsten filament of JEOL has a strong vacuum system, which is widely applied in a SEM (scanning electron microscope). EB tungsten filament of JEOL uses the newest electro-optical systems to enhance the image quality scanning electron microscope. The main specifications of EB tungsten filament of JEOL are 0.55mm of mosquito type, 0.65mm of mosquito type, 0.8mm of mosquito type, 0.8mm of eccentric type and 0.55mm of half-moon type. EB tungsten filament of JEOL has a strong plasticity in maintaining electron gun and optical coating.

EB tungsten filament of JEOL is made of tungsten with a high-grade.  Its features are high melting point and low coefficients of thermal expansion. This kind of tungsten is the best material for EB tungsten filament. The main types of EB tungsten filament of JEOL is K type. The diameter of its ceramic plate is 28.0 mm, the pin diameter is 1.2 mm, and the distance of center pin is 8.0 mm.

electron gun filamentJEOL electron gun filament

Tungsten Metals Supplier: Chinatungsten Online www.tungsten.com.cn  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

Tungsten Copper Powder CIP Process

Category: Tungsten Information
Published on 14 April 2016

Compared with HIP (Hot Isostatic Pressing) process, CIP (Cold Isostatic Pressing) is a kind of molding process that commonly all directions sealed in plastic mold material simultaneously even pressure at room temperature, and more for powdered metal or non-metallic materials, molding, which provides a pre-sintered compacts for sintering. Tungsten copper is a kind of psudoalloy consists of W and Cu mutually soluble and has a great difference in physical and chemical properties. So it is difficult to prepare by conventional methods, which must be prepared by PM (Powder Metallurgy) process. According to different pressure transmission fluid, including cold isostatic wet bag method and the dry bag method isostatic pressing and soft mode.

Since the conventional molding method between the powder and the powder, powder and punch and die wall there is a certain friction, so that during the pressing force distribution and transmission of certain changes occur, and also resulted in various parts of the compact density and intensity distribution uneven; by comparison, CIP has more uniform forming pressure, which can ensure under lower pressures have pressed leather uniform density and integrity of shape and small loss of mold, high molding efficiency.

In addition, it should be noticed that pressing speed controlling is also a significant factor of the blank density during CIP process. It not only affects the state of friction and work hardening powder particles, but also affects the case of gas escaping. If the compression speed is too fast, the gas can not escape easily, which left in the blanks in the relatively more in the subsequent sintering process are correspondingly difficult to eliminate left voids or pores. Furthermore, pressing too fast will make the inside of the powder aggregate greater stress, resulting in relief the compacts elastic aftereffect. Therefore, in the process of compacting, reduce the speed and extend the dwell time appropriately can ensure that pressure transmission fully, air between powders have sufficient time to escape and be beneficial for density distribution.

Tungsten Carbide Supplier: Chinatungsten Online tungsten-carbide.com.cn Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News&Tungsten Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

Tungsten Carbide Transferring Ball

Category: Tungsten Information
Published on 14 April 2016

Tungsten carbide transferring ball, as the name suggests that it is a kind of flexible sphere can run in all directions. So it also has been called universal ball, transferring roller or bull’s eye, etc. Due to the flexibility universal ball rolling, the work bench or other original material quality or bulky workpiece can be more portable to slip, which also greatly reduces the labor intensity of the operator. Universal ball is suitable for transporting the items with smooth and strong surface of bottom, such as cardboard boxes, plastic crates, pallet parts, and surface roughness of the steel sheet-like object. In addition, according to different load requirements, it can adjust the density distribution of transferring ball, or can choose transferring ball with different materials and carrying capacity.

Commonly transferring ball materials includes steel ball, stainless steel ball, carbon steel ball, bearing steel ball, galvanized steel ball, plastic steel ball, tungsten carbide ball and so on. By comparison, tungsten carbide transferring ball has the better properties among them. Tungsten carbide is composed of WC and Co, WC has higher hardness and Co added improves the toughness, strength and wear resistance. It by carbide ball and the support base with the completion of transfer of the workpiece. Tungsten carbide transferring ball has higher machining accuracy and the surface without secondary treatment.

The surface toughness of common steel ball can not meet the requirements, which electrically galvanized or chrome effect will be affected. And secondary processing if the grinder be polished, dimensional accuracy will be affected to some degree. Except surface quality, there are several evaluation parameters of universal ball overall quality, such as flexibility, noise and dimensional accuracy. Generally, plate with your fingers on the ball was moving moment of inertia of the ball more than three seconds for qualified. The noise is related with ball accuracy and the quality, tungsten carbide ball has higher accuracy and quality so its noise is lower and the rotation is smoother and more uniform.

Tungsten Carbide Transferring Ball

Tungsten Carbide Supplier: Chinatungsten Online tungsten-carbide.com.cn Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News&Tungsten Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

Tungsten Trioxide Denitration Catalyst Selection of High Ash Working Condition

Category: Tungsten Information
Published on 13 April 2016
Honeycomb denitration catalyst has a large surface area due to a large number of holes, small intercept, thin wall, thus to require smaller amount of engineering tungsten trioxide denitration catalyst. However, because of its smaller aperture, the property of flue gas passing through is poor, fly ash blocking the bridge is easily occurred at high fly ash conditions; when part of the aperture blocked, the amount of fly ash will have a sharp increasing in the other aperture, and then the whole catalyst occur serious blockage. We know that the catalyst blockage is a serious irreversible running accident, which has to exit the reactor catalyst to clean up when the situation is serious.

SCR denitration catalyst
 
Since the thickness of the thin-walled catalyst is average 25% or more smaller than the standard, the pore size is about 5% larger than the standard when at the same number holes, thus to have a better smoke and ash passing through, higher specific surface area , lower engineering required. However, since the thin wall thickness, the wear-resistant is reduced, and partial rupture may be occurred, or even blocked, finally bring a high operating costs.
 
The majority of our thermal power combustion conditions are poor which demand very large catalyst regeneration. The selection of catalyst sufficient to consider is not only the life of the chemical mechanical strength, but also the mechanical strength required for catalyst regeneration. Under conditions of high fly ash, ignoring design principle, blindly select long and short type catalyst is not desirable. In general, the smaller thickness, the higher the risk of mechanical damage is; besides, these risks will not ease with the hardening end. According to the experience when the fly ash concentration exceeds 30g/Nm3, the catalyst should be used in standard-type catalyst with wall thickness greater than 1.0mm in order to fully meet the requirements of chemical and mechanical life, and the risks of plug fouled and worn does not occurred.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

WO3 Denitration Catalyst Uses Titanium Dioxide

Category: Tungsten Information
Published on 13 April 2016
Denitration catalyst nano-titanium dioxide is a kind of titanium dioxide, the powder which doped with tungsten trioxide, vanadium pentoxide. The catalyst powder may be supported on a stainless steel plate, ceramic, glass fiber base material, and then shaped in a plate, corrugated honeycomb or plate, finally integrated in the steel to composite of the overall denitration reactor. Denitration catalyst comprising tungsten with titanium dioxide has the nice properties such as high hydrophilicity, strong adsorption, high specific surface area and catalytic activity, stable surface area when sintered under high temperature at 600℃, no secondary pollution, thus mainly used for denitration, which the denitration rate can up to more than 95% under the condition of 100% flue gas.

nano titanium dioxide
 
SCR is the most effective denitration technology currently, the denitration catalyst containing tungsten trioxide is a denitration catalyst with excellent performance. Compared with traditional SCR catalyst, this catalyst has a larger surface area, particle uniformity, low sulfur content and high catalytic activity, and thus having a stronger catalytic reduction. Denitration catalyst titanium dioxide containing with tungsten is mainly used for the manufacture of a denitration catalyst, a good carrier material for SCR denitration catalyst, mainly dealing with nitrogen oxides, specifically for waste incineration and chemical plants, oil refineries, coke, flue gas treatment, and automotive glass factory, ship exhaust gas treatment required for denitration catalyst manufacturing.
 
If the catalyst exposures at 450℃ for a long-term, it will easy to cause prone catalyst sintered, thus leads to the TiO2 catalyst particle changed, specific performance like that the surface area reduced, activity decreased, but the introduction of tungsten trioxide can reduce the sintering of catalyst at maximum. Furthermore, tungsten trioxide evenly distributed in the surface of titanium dioxide, and catalyst efficiency has been further improved after it combined with vanadium pentoxide.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

The Classifications of EB Tungsten Filament

Category: Tungsten Information
Published on 13 April 2016

All EB (electron beam) tungsten filaments are made of tungsten which is also known as wolfram. The EB tungsten filament has a good discharge performance and an excellent anti-sag performance. The two characteristic can ensure that the filament is not deformed during working. The following classifications are the main types of EB tungsten filament.

Classification

Specification

Picture

Mosquito Coil: the shape of the EB tungsten filament is similar to the mosquito coil, therefore, it can be named as Mosquito Coil. And the Mosquito Coil can be divided into the following specifications.

0.55mm

electron gun filaemnt 0.55

0.65mm

electron gun filament 0.65

0.80mm

electron gun filament 0.8

Pull-type: Pull-type is also known as the cavity type of Mosquito Coil.

0.80mm

electron gun filaemnt 0.8

Classification

Specification

Picture

U-shaped: this kind of  EB tungsten filament is similar to the shape of the letter U.

0.80mm

electron gun filaemnt U 0.8.

U-shaped with folding legs: the feet of the EB tungsten filament has a curved.

0.80mm

electron gun filaemnt Uz 0.8.

Half Moon: the shape of this type is the shape of a half moon.

0.80mm

electron gun filaemnt half moon 0.8.

Straight shape

0.80mm

electron gun filaemnt straight 0.8.

Tungsten Metals Supplier: Chinatungsten Online www.tungsten.com.cn  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

Low-NOx Combustion Unit Uses Tungsten Trioxide SCR Denitration Catalyst

Category: Tungsten Information
Published on 13 April 2016
The two major mechanisms of NOx formation in low-NOx combustion unit are while reducing combustion temperature, the concentration of oxygen in the fire zone also be reduced, in order to suppress the formation of nitrogen oxides in the furnace. The concentration of NOx emissions can be reduced by 30% to 60% by using low-NOx combustion furnace technology. Nowadays, the widely used low-NOx combustion technology is mainly through low-nitrogen furnace transformation, for achieving the goals of low-oxygen, hierarchical partitioning combustion in the furnace, thus to achieve the reduction of NOx emission.

flue gas denitration equipment
 
Due to the limitations of the furnace low NOx combustion technology, the NOx emissions can’t meet environmental requirements, so denitration process should be carried out in order to further reduce NOx emissions. Dry, semi-dry and wet method ate the prevailing flue gas denitration processes. Wherein, dry SCR denitration process is of high commercial value and being widely used with its nice properties, such as simple structure, easy operation, high reliability, high denitration efficiency, relatively low initial Investment.
 
SCR device consists of denitration reaction preparation system and the composition of the reactor body, reducing NOx into nitrogen and water vapor by injecting into denitration reaction agents--NH3 into the reactor. SCR denitration catalysts are generally taking titanium dioxide as a carrier, vanadium pentoxide and tungsten trioxide as the main active ingredients, its activation temperature is generally between 300~400 ℃. Tungsten trioxide plays the role of anti-curing, anti-poisoning in the catalyst, thus to enhance the activity of the catalyst. SCR denitration reactor can be divided into high and low dust categories according to installation location of precipitator. However, due to low dust device needs to install a steam heater and flue gas heat exchanger (GGH), which makes the system complex, investment increased, so the generally chosen is the high dust process.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

CaO Effects Designing WO3 Denitration Catalyst

Category: Tungsten Information
Published on 13 April 2016
denitration catalystCalcium oxide (CaO), the so-called quicklime, is an inorganic compound powder with white, hygroscopic and corrosive. The plaster (Calcium sulfate) in thermal power plant is generated by sulfur dioxide reacting with desulfurization and then oxidized, and then discharged with the flue gas exhaust system. When it comes into being that calcium sulfate contacts with tungsten trioxide SCR denitration catalyst, large number of calcium sulfate will be deposited on the surface of the catalyst, which can cause the catalyst surface shielding, and then the catalyst activity decreased.
 
By the time the content of calcium oxide in the flue gas is less than 5%, little effect has occurred on catalyst design. However, when the content of calcium oxide is more than 5%, its effect on the catalyst design generates becomes very large. With the calcium oxide content increasing, the amount of tungsten trioxide SCR denitration catalyst turns to linearly increasing trend, especially when the calcium oxide content is about 30%, the consumed catalyst required will increase about 25% compared with low calcium conditions. In this condition, catalyst activity and aging speed can’t overestimate when design catalyst; in order to ensure the chemical catalyst lifetime (24,000 hours), we need to leave enough adequate catalyst, thus will result in a larger number of design volume and costs increased.
 
Therefore, in the high calcium conditions, the blind pursuit of a minimum amount of tungsten trioxide SCR denitration catalyst will result in a short life of the catalyst, reduction denitration efficiency decreased and other adverse consequences. Besides, if we ignore the impact of calcium on the running of catalyst, reduce design margins unprincipled, overestimated the catalyst activity, the risk of high operating costs will present although it bring cost savings to some extent. It is worth mentioning that, the presence of tungsten trioxide can effectively inhibit the sintering of the catalyst particles, delaying the degree of sintering, therefore, tungsten trioxide SCR denitration catalyst is particularly suitable for high calcium conditions.
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

Tungsten Bronze (TB) Crystal Structure

Category: Tungsten Information
Published on 13 April 2016
The tungsten bronze (TB) crystal material, due to good optical effects, electrical properties and blastic phase boundary and so on, has been widely used in the technical field of laser frequency doubling, optical modulator, optical information processing, superconducting, humidity sensors, fuel cells and other solids. Molecular design of TB crystal material is to design on the atomic level, explore and synthetic crystalline material of the target structure based on the understanding of its structure. In recent years, this area has made a lot of new results, which becomes an effective means of research and development and improved performance of this type of crystal material.
 
Tetragonal tungsten bronze (TTB) crystal is relative common of tungsten bronze type crystals, (many rhombic TB structure is a superstructure of TTB structure), which is widely used. So the commonly known TB crystal mainly refers to the TTB crystals. the structure projection of C-axis shown in FIG. B-O octahedra corner-top connection formed pentagonal, square and triangular pores. They are called A1, A2 and C positions. The thick solid line drawn is a unit cell, wherein: the number of void ratio down to A1: A2: C = 4: 2: 4, ie there are10 positions of A totally; and 10 positions of B and 30 of O2 -.
 
B position can be divided into two B1 position (cell edges midpoint) and eight B2 position (cell interior) based on symmetric types. C axis translation period equals to the height of a B-O octahedron . In the structure: coordination number of A2 and O2- may be 9,10,11,15, ligand effect of A2, C, B and O2- respectively are 12,9 and 6.
 
Therefore, the formula of TB structure is (A1) 1 (A 2) 2C4 (B1) 2 (B2) 8O30. When six A1, A2 positions are not filled with cation and C position is completely empty, it is called not filled structure; when six A1, A2 positions are all filled with cation and C position is completely empty, it is called full structure; When six A1, A2 positions and C position are all filled with cation, it is called completely filled structure.

TB structure
Tungsten Oxide Supplier: Chinatungsten Online www.tungsten-oxide.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
Tungsten News & Prices, 3G Version: http://3g.chinatungsten.com Molybdenum News & Molybdenum Price: http://news.molybdenum.com.cn

 

Page 515 of 1117

  • Start
  • Prev
  • 510
  • 511
  • 512
  • 513
  • 514
  • 515
  • 516
  • 517
  • 518
  • 519
  • Next
  • End
 

WeChat

 

Latest Articles

  • Tungsten Scrap Prices Rise - October 26, 2026
  • Ferromolybdenum Prices Lowered - October 26, 2026
  • Light Rare Earth Prices Under Pressure - October 26, 2026
  • Tungsten Concentrate Prices Rise 12% This Week - October 23, 2026
  • Molybdenum Powder Prices Fall 3.7% This Week - October 23, 2026
  • Rare Earth Market - October 23, 2026
  • Scrap Tungsten Carbide Rod Prices Rise - October 22, 2026

Login Form

  • Forgot your password?
  • Forgot your username?

Link

  • Chinatungsten Online
  • Tungsten Video
  • Tungsten Information
  • Tungsten Image
  • Tungsten Blog
  • Molybdenum News
  • Tungsten Metals
  • Tungsten Alloy
  • Tungsten Carbide
  • Tungsten Powder
  • Tungsten Jewellery
  • Molybdenum
  • CTIA GROUP
  • Links