At present, cryogenic treatment mainly applied in tool steel, non-ferrous metal applications under development step, here we discuss that the tungsten copper contacts cryogenic treatment process conditions affect its properties. Tungsten copper contact is a psudoalloy, which is composed of two kinds of immiscible and has a great difference in physical and chemical properties metals. There is no phase change in the reaction and it is brittle so that it is difficult to adapt conventional heat treatment hardening process to improve its relative performance. Cryogenic treatment is undoubtedly an ideal choice.

Viewed from the micro-structure, after cryogenic treatment, W matrix disperse a large number of Cu phase and the organization has significantly refined, which is due to precipitation of Cu solute in W after cryogenic treatment. In addition, it also can be found that with the increase in the copper content, the segregation phenomenon is also becoming increasing apparently. Copper particles dispersed precipitated tissue thinning, and atomic displacement volume shrinkage, tungsten copper contact density and overall strength has also improved.

While its hardness and strength has greatly improved after cryogenic treatment, and electrical conductivity with increasing tungsten content decreases. This is due to cryogenic treatment makes a lot of precipitated Cu and W form a solid solution, and is proportional to the electrical conductivity of tungsten copper contacts with the copper content. Overall, tungsten copper contacts after cryogenic treatment, may be little alternative to tungsten copper copper-tungsten less, not only improves performance, but also reduce costs.

Cryogenic treatment refers to process the blank at -190℃-230℃, which has a broad application prospect, such as non-ferrous metal, ferrous metal, metal alloy, carbide, plastic, silicate and so on. The basic principle is that in the process of metal hardened to cooling by heat treatment, which produces alloy and carbon dissolved and combined with the formation of austenite(Austenitic is a lamellar microstructure, usually ɣ-Fe solid solution in a small amount of non-magnetic solid solution of carbon) and diffusion; in the cooling process, since the low temperature produce suppress the formation of martensite(The crystal structure of martensite is body-centered tetragonal (BCT). High carbon steel is usually accelerated cooling to obtain such organizations and high strength and hardness of steel is one of the main features of martensite.), the final transition point (Mf) is definitely low.

Austenite is very unstable and easily decomposes at low temperature, so the original defects (pores and internal stress concentration part) and becomes plastic flow structure refinement. Therefore, as long as put the metal at ultra-low temperature, the austenite is converted into martensite, which eliminates the internal stress. In addition, due to the contraction of the tissue volume at ultra-low temperature, Fe lattice constant decreases and the driving force to strengthen the precipitation of carbon atoms, so a lot of martensitic matrix deposited ultrafine carbides. The strength of these ultra-fine crystalline materials will improve and increase the wear resistance and rigidity. And Ultra-low temperature can also be transferred metal atom transport capacity, which makes the atoms can not be separated and become closer.

There are some experiments shows that high-pressure vessel after cryogenic treatment can meet the requirements of the strength of solid propellant rocket; some down-hole equipment for sour oil field after cryogenic treatment can improve the corrosion resistance and the welding cracks; some parts of the alloy cryogenic treatment, volume stability, dimensional stability and strength has been greatly improved.

As a kind of tungsten metal products, tungsten crucible has some very excellent properties, such as a high melting point, a high boiling point, a strong anti-friction resistance and the coefficient of thermal expansion is very small. Nowadays, tungsten crucible is widely used in rare earth smelting, quartz glass, electronic spraying and other industries because of those excellent properties. Moreover, China is the most resource-rich countries of tungsten in the world. Therefore, the related applications of tungsten crucible have also been rapid development. According to the manufacturing process of the tungsten crucible, it can be mainly divided into two types: forging type and sintering type. The two types will be briefly described in the next part.

Forging Tungsten Crucible: Forging process is a manufacturing process which can make metal billet become plastic deformation by using localized compressive forces to obtain the forging parts with a mechanical energy, and a relatively shape and size. The raw material of forging tungsten crucible is a solid tungsten rod. After processing of the lathe system, then tungsten crucible can be produced. The advantage of the forging tungsten crucible is a high density. What’s more, it is not susceptible to be corroded with a longer life time.

Sintering tungsten crucible: It refers to a conventional sintering process which would make powdery raw materials into the dense bodies. The raw material of sintering tungsten crucible is tungsten powder. After firing the molding, sintering tungsten crucible would be produced by lathe working. Sintering tungsten crucible can be characterized by the production of large-size of tungsten crucible.

Tungsten crucible has a high temperature oxidation resistance and resistance and a strong electrochemical corrosion resistance, so it is a relatively good material for high temperature supporting. Although there are many advantages of forging tungsten crucible and sintering tungsten crucible, there still exist some serious problems. For example, during the sintering process of the sintering tungsten crucible, agglomerate cannot deliver the heat to the blast furnace because of the high temperature. Even if people can recover the part of the waste heat, sintering processing still release a large amount of waste heat. It would have a great effect in ecological environment. In terms of the environment, people should know more about the recovery details of it to improve the development of tungsten industry.

Plasma spraying process: First of all, users should prepare a suitable graphite mandrel for finished tungsten crucible product, and then fixed it on an airtight turntable. When sealed housing is in a vacuum condition, and then adds argon with a high purity. After spraying the surface of graphite mandrel by plasma spraying equipment, spraying it until the size and the quality can meet the design requirement. And it is time to cool it. Finally, tungsten crucible can be formed by machining process.

Chemical vapor deposition (CVD): It is a chemical process used to produce high quality, high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. If people want to use this way to produce tungsten crucible, the main raw materials are tungsten hexafluoride and hydrogen. Both of them can be oxidized into vapor deposition of tungsten atoms. After that, there exist settled player of tungsten on surface of matrix. Until the settled player increase to a certain degree, basic shape of tungsten crucible is formed. Finally, a finished tungsten crucible will be produced by the treatment process and annealing process.

Rivet linking and welding process: This process includes rivet linking and welding. Rivet linking refers to two or more metals are linked by rivets, and people often use rivet to link two tungsten plates. Welding is a manufacturing or sculptural process that joins materials, usually metals or thermoplastics, by causing fusion, which is distinct from lower temperature metal-joining techniques such as brazing and soldering, which do not melt the base metal. Use this way to produce the tungsten crucible, the first step is to make tungsten plates into tungsten tube. And then, link it with a round tungsten plate to produce the finished tungsten crucible.

Tungsten crucible belongs to the deep processing of tungsten products and it has a very high added value. Therefore, many researchers are working on manufacturing techniques of tungsten crucible. So far, manufacturing techniques of tungsten crucible have been widely used in various products. The most common process is isostatic - sintering process, forging and Rivet linking and welding process. Manufacturing techniques of the three processes are more mature, and quality and stability of production are better by using the three process.

With the rapid development of tungsten industry, the market demand for tungsten crucible is gradually increased, and the requirements of quality for product are more strictly. Therefore, the manufacturing techniques and properties of tungsten crucible play a significance role in the development and utilization of tungsten materials. There will be a brief analysis of these threemanufacturing techniques.

Isostatic - sintering process: Nowadays, it is one of the most important manufacturing techniques for the industrial tungsten crucible production. This technique consists of preparing raw materials, loading powder, isostatic pressing, sintering at a high temperature, lathe processing, product testing, etc. First of all, mold should be assembled according to the required size of products. And then tungsten powder material that has reached the national standard should be put into a mold and the mold must be sealed immediately. Next is to put it in an isostatic press with a pressure of 180-250MP. After that, the pressed compact should be sintered in a high temperature induction sintering furnace under super-heating rate sintering between 80 degrees centigrade and 150 degrees centigrade one hour. The holding time should last for 4 or8 hours. Finally, process the product in accordance with its requirement. After processing, it is time to test the appearance size, density of finished product.

Forging process: Forging process is a manufacturing process involving the shaping of metal using localized compressive forces. Adopting this process to make tungsten crucible mainly consist of three steps: billet preparation, forging and machining. In general, the relative density of the billet is between 90% and 95%. In the preparation of the billet, the size and quality of the tungsten rod are needed to calculate in accordance with the requirements of the finished product. Then put the tungsten rod in a hydrogen furnace to heat under a temperature of 1400-1600 ℃. After keeping warm for a while, forging the billet, and then repeated heating and forging billets for some times until the size of billet meet the requirements. After the forging, the billet can be annealed, and then processed in accordance with the size and the outlook of the finished product.

Spinning process: When use this method for making tungsten crucible, users should prepare tungsten billet before. And then make it into a sheet which conforms to the design by hot-rolling process to hot-rolled, and process it into a few pieces of wafers, and put it on a hot spinning machine. After that, heating mixed flame which consists of hydrogen and air mixing. And after spinning for several times, the shape tungsten plate becomes the shape of the tungsten crucible, and finally cools it into finished tungsten crucible.