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  2. Tungsten Information

Supported WO3-Based Oxidative Desulfurization Catalyst

Category: Tungsten Information
Published on 27 April 2016
WO3 desulfurization catalystOxidative desulfurization process consists of two steps: Firstly, oxidize the organic sulfur compounds in the oil into polar sulfone substance; secondly, separate the sulfone substances to achieve the purpose of desulfurization by adsorption, extraction and distillation methods s. Wherein the transformation of sulfone substance is the key step.
 
Sulfone is a group organic compound which contains sulfonyl, and often combined S with two carbon atoms (e.g. two hydrocarbons or simple divalent), generally the stable crystalline compounds, can be generated by the oxidation of organic sulfides or other methods.
 
Supported WO3-based oxidative desulfurization catalyst is achieving deep desulfurization by the oxidation catalyzed reaction of organic peroxide and sulfur heterocyclic aromatic compounds under mild conditions. The preparation program is under a hydrogen atmosphere or an inert gas atmosphere, plasma treatment supported tungsten trioxide based catalyst.
 
Preparation process are as follows:
1. The equal volume dipping method to prepare supported WO3/SiO2 catalyst: Weigh 0.852g of ammonium metatungstate and dissolved in 9ml of dubbed deionized water to form a solution and dripped drop by drop into the 3g silica with stirring;
2. Static in the room temperature for 12h, and then dried at 120°C for 4 hours;
3. Raise the temperature by the rate of 2V/min to 500 ° C, calcined for 5 hours to obtain the tungsten trioxide silica supported catalyst, wherein the loaded tungsten trioxide amount is 20% of the mass fraction of (of the total catalyst mass meter);
4. Under Ar atmosphere, treating the WO3/SiO2 catalyst with plasma;
Put 2mL of catalyst in the dielectric barrier discharge plasma reactor; control the Ar gas flow rate at 100mL/min under normal pressure; discharge frequency of plasma is about 10kHz; the input voltage of 50 volts; the input power of about 15 watts for 30min, and then get the supported WO3-based oxidative desulfurization catalyst.
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WO3 Used for Ultra-Deep Oxidative Desulfurization Catalyst

Category: Tungsten Information
Published on 27 April 2016
desulfurization catalystSulfur compounds present in the oil refining process will not only make catalyst in the cars and purification system irreversibly poisoned, but also the Sox into the combustion air can cause serious environmental problems such as acid rain; in addition, the new fuel cell applications also require extremely low or zero sulfur content, thereby, the removal of sulfur compounds has been increasing interested subject.
 
Hydrodesulfurization (HDS) technology is currently the commonly used of oil desulfurization technology in the industry, which the working principle is converting organic sulfur compounds into hydrogen sulfide the hydrogenation and then discharging out, thus to achieve the purpose of desulfurization. HDS has good removal efficiency for most sulfur compounds, but has the difficulties such as large investment, high costs, lower quality of oil and its impact on the thiophene sulfide removal. Therefore, a novel of oxidative desulfurization (ODS) technology with advantages of mild operating conditions, low investment and low cost of thiophene sulfides effectively remove has attracted much attention.
 
The expression of this kind of ultra-deep oxidative desulfurization catalyst is: [HqSexMyOz], wherein, M maybe on behalf of W, Mo, Ti, V, Ru. Tungsten trioxide because of its unique properties, often as a catalyst in the petrochemical industry, it can be used as a raw material for preparing such a catalyst.
 
It used in the preparation of ultra-low sulfur oil maybe display by the following steps:
1. Place the oil, 0.02% ~0.2% the amount of oil quality of [HqSexMyOz], 1~20 times (molar ratio) the amount of sulfur content of the oxidant and solvent in the reactor, carried out a reaction at 20°C~80°C, under normal pressure, with stirring for about I0min and then stop stirring;
2. Recover oil, catalyst and solvent by separating, and removing the oxide product by means of certain post-treatment to obtain the ultra-low-sulfur oil.
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Tungsten Trioxide Used in Hydrodesulfurization Catalyst

Category: Tungsten Information
Published on 27 April 2016
desulfurizerIn recent years, with the quality petroleum feedstocks becoming poorer with the sulfur impurities increasing, more and more harmful gases SOx have been discharged into the atmosphere, causing serious environmental pollution. With the increasing of people's awareness of environmental protection, as well as harmful emissions standards becoming more and more stringent, the desulfurization technology has becoming more and more important. Currently the commonly used method in the oil refining process is the hydrodesulfurization desulfurization, which is carried out catalytic hydrogenation under certain temperature and pressure, thus to remove the S in the form of hydrogen sulfide. There are many affecting factors of oil hydrodesulfurization efficiency, and performance of the catalyst is the key.
 
1. Calcine the waste oxidized aluminum at a temperature of 450~550°C for 2~4 hours, cooled to room temperature and crushed;
2. Uniformly mix the active ingredients-tungsten trioxide (active ingredients may be one or more kinds of nickel oxide, molybdenum trioxide, tungsten trioxide, cobalt oxide), waste oxidized aluminum after treated, additives (including at least one of Binder U, pore-forming agent) with stirring;
3. Kneading, forming to obtain a molded material;
4. Put into an oven to dry under 100°C for 2 hours;
5. Calcined for 2 hours under 460°C, thus to obtain hydrodesulfurization catalysts containing tungsten trioxide which is desired.
 
Wherein the calcination temperature of waste oxidized aluminum is limited between 450~550℃, it is because at this calcination temperature and time, the binder and pore-forming agent to fill the original pore volume can be maximum reduced, thus the oxidized aluminum agent itself the pore volume and pore size can be maximize improved; besides, the raw materials to meet the requirements of preparation of hydrodesulfurization catalyst by kneading method, and its products - hydrodesulfurization catalyst containing tungsten trioxide has good catalytic activity.
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Tungsten Copper Heat Sink Plasma Spraying (2/2)

Category: Tungsten Information
Published on 27 April 2016

The researchers use two kinds of spray gun (internal and external powder feed) to observe the structure and properties of tungsten copper heat sink. It can be found that in the internal powder feeding conditions, W content of tungsten copper composite material is higher than the content of external powder feed. This is due to internal feed powder is powder being ejected before the gun are all located in the plasma flame, part of the W particle is melted, melted and un-melted W particles, and the molten copper solution together is sprayed into the substrate, so that easy obtain raw material powder composition approximating tungsten copper composite material; while in the process of external powder feed, he trajectory of the powder particles are not entirely consistent with the plasma flame, which can only make a fraction of smaller particle size of the W particles melt, and a lot without melting of W particles are difficult to be deposited, so the W collected rate decrease.

Besides, at internal powder feeding conditions, only a small amount of cuprous oxide can be detected, which indicates the impact of power in copper oxidation is not obvious. This is due to the internal powder feeding only a very small amount of oxygen is brought into a powder particle flow, thereby largely avoiding the oxidation of copper; by contrast, in the same power, a large number of external powders feed oxygen into the powder particles flow and exacerbates the copper oxide. With the power increase, the plasma flame temperature also increases, the oxidation of copper increased significantly. Overall, plasma spraying uses plasma arc, which compared with free arc has fine arc, high current density, and high degree of gas ionization. So it has many advantages, such as high temperature, high energy concentration, excellent arc stability, which is the ideal material for tungsten copper heat sink.

Tungsten Copper Heat Sink Plasma Spraying

Tungsten Copper Supplier: Chinatungsten Online tungsten-copper.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Tungsten Copper Heat Sink Plasma Spraying (1/2)

Category: Tungsten Information
Published on 27 April 2016

With the rapid development of science and technology, integrated in the microelectronics industry sectors related electronic products have become more sophisticated, the corresponding energy consumption also increased. So it places higher demands on heat sink properties, which not only required high density and strength, but also has excellent electrical conductivity, thermal conductivity and low coefficient of thermal expansion. Tungsten copper is composed of W with high hardness, high density, high strength, high melting point and low coefficient of thermal expansion and Cu with perfect electrical and thermal conductivity so that it can be an ideal material for heat sink. Furthermore, the properties of tungsten copper heat sink can be improved by the adjustment of W and Cu content.

Since there is a great difference in physical and chemical properties between W and Cu, which has 2000℃ difference in melting point. Both of them do not form a compound or solution, so it is a kind of typical pseudo alloy. Therefore, it is difficult to achieve by common pressed and sintered, the infiltration is the best way. But infiltration is easy to form pores certain deficiencies and to bring some difficulties to the subsequent processing. Plasma spraying is a strengthening of the material surface and surface-modified new multi-purpose precision spraying techniques. It uses plasma arc drove by DC as the heat source and has the following characteristics:

1. Ultra-high temperature characteristics, suitable for spraying refractory material;

2. High particle injection rate, the coating is dense and has higher bonding strength;

3. In the process of spraying, inert gas used as the shielding gas so that the coating material difficult to be oxidized.

Plasma spraying technique can make the surface of the substrate with a high temperature oxidation, thermal insulation, anti-friction, wear and corrosion, insulation, radiation protection and sealing properties, which can heat metal, alloy and ceramics to molten or semi-molten state and spray to the surface after pretreatment at high speed to form a firmly attached layer. In addition, plasma spraying also can be used in medical field, the coating layer of a few microns in artificial bone surface coating can achieve enhanced affinity for artificial bone and the strengthening effect.

Tungsten Copper Supplier: Chinatungsten Online tungsten-copper.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Tungsten Alloy Radiation Shielding For IDC Room

Category: Tungsten Information
Published on 26 April 2016

tungsten alloy radiation shielding for IDC roomTungsten alloy radiation shielding for IDC room is a radiation shielding used to shield electromagnetic radiation generated by IDC room. IDC room, also known as Internet data center, is the standardized telecom room established by the telecom department through utilizing the existing bandwidth resources and Internet communications lines. With the evolving needs of Internet, IDC room rapidly develops into a vital part of China's Internet industry in the new century, to provide professional server rental managed services and related value-added services for the media, enterprises, Internet content providers, government, business or web server group. Therefore, the enterprises or government agencies no longer need to establish their own IDC room,lay the expensive communication lines, and hire network engineers with the use of IDC server hosting business.

Due to IDC room equipments will release large amounts of electromagnetic radiation which is harmful for human body, staffs can use tungsten alloy radiation shielding for IDC room to shield radiation. Electromagnetic radiation has thermal effects, non-thermal effects and cumulative effects on the human body. According to experts, electromagnetic radiation  more than 2 gigahertz will cause people to suffer from diseases, such as skin disease, cardiovascular disease, vitiligo, psoriasis, allergic purpura and diabetes, and lead to eyelid edema, bloodshot eyes, stuffy nose, runny nose, sore throat discomfort, or systemic skin urticaria, eczema, itching. Long-term and excessive electromagnetic radiation will also damage human reproductive, nervous and immune system, changing blood, lymph and cell protoplasm, causing fetal malformation or spontaneous abortion.

Tungsten alloy radiation shielding for IDC room mainly uses tungsten heavy alloy. According to the research, the radiation shielding performance of a metal material is closely related to its density, the radiation shielding ability increase with the increasing of density. Due to the high density of tungsten alloy, tungsten alloy radiation shielding for IDC room thus has high radiation shielding properties, which can effectively shield the electromagnetic radiation generated by the IDC room equipment, to reduce the radiation damage on staffs. Moreover, tungsten alloy is a harmless and non-toxic material that will not produce harmful substances or pollute the environment. 

Tungsten Alloy Supplier: Chinatungsten Online www.tungsten-alloy.com  Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Five Tips for Successful Aluminum GTAW-Tungsten Electrode Choosing

Category: Tungsten Information
Published on 26 April 2016
As we know, alloyed aluminum is widely used in manufacturing industries such as transportation, aerospace, automotive, power transmission, and construction. Because it is not only lightweight but strong, corrosion-resistant, can be machined easily, is a good conductor of electricity, and it has an aesthetically pleasing appearance. But aluminum is difficult to weld, especially using gas tungsten arc welding (GTAW). So well control the every parameter in GTAW is need for successful aluminum welding. You need to well understand metal’s unique properties and the welding preparation techniques and tools you’ll need to address those properties.
 
There are 5 tips for successful using GTAW for aluminum welding.
1. Remove the oxide layer of base aluminum before welding, which can be done either chemical method or physical method. 
2. Choose the right shielding gas. People usually choose argon as shielding gas in GTAW applications. But it is reported that helium is more suitable for GTAW welding, because helium provides you with a hotter arc that ionizes at a higher temperature, namely more power for your amperage setting and better control. 
3. Choose the right tungsten electrodes. In the past, pure tungsten (EWP) and thoriated tungsten (EWTh-2) were the preferred choices for aluminum GTAW. But today rare-earth tungsten electrode (EWG) is an excellent choice for welding aluminum or any other metal. Because rare-earth can provides good arc starting at low amperage and burnoff rates and without radioactive properties. Tungsten electrode has low burnoff rate means the tip geometry lasts longer and the tungsten won’t melt as easily, which not only can prolong electrode’ life, but can minimize weld zone contamination. 
4. Select AC for aluminum GTAW. This is because AC can provide cleaning property of the power source to remove oxide layer in the basic material. 
5. Invest in a High-quality Torch
thoriated tungsten electrodes for GTAW
 
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WO3 Used in Hydrodesulfurization Catalyst

Category: Tungsten Information
Published on 26 April 2016
tungsten oxide desulfurizerThe WO3 hydrodesulfurization catalyst with nanoscale, high dispersion and activity which can be used in the process of distillate hydrodesulfurization, and carried out in a fixed bed reactor, at a reaction temperature of 200-400℃, pressure of 0.2-20MPa, its production steps are as follows:
1. Dissolve the tungsten oxide in the concentrated hydrochloric acid, and carried out electrolysis to generate the hydrochloric acid solution containing with tungsten trioxide;
2. Inlet the hydrogen sulfide gas to get a vulcanization reaction, wherein the gas flow rate is 60~200ml/min, the vulcanizing agents can be in place of ammonium polysulfide, lee sodium sulfide, ammonium sulfide;
3. Taken out oxidation under the condition of oxygen or air at 60~120℃ for 24~56 hours;
4. carried out decompression and distillation to get the mixture, then diluted with hydrochloric acid, filtered and separated by resin column to obtain a core sulfur-containing transition metal atom clusters which are as the following clusters: [M 2 OnS 2 -n] m +, [m 3 OnS 4 -n] m + or [m 4OnS6;-n] m + a, wherein m = W, n = 0~6, m = 0~6;
5. The products obtained in Step 4 are loaded to kinds of carriers by dipping or ion exchange method under the oxygen content of less than 0.1% of an inert atmosphere (helium, argon or nitrogen), then you will get the sulfur catalyst loading type of transition metal atom clusters, which is the needed--tungsten trioxide hydrogen desulfurization catalyst.
 
The prepared catalyst has the following advantages:
1. Raw materials are simple and easy to get with low cost, mild preparation conditions, simple operation;
2. Compared with the traditional metal catalysts, it has the similar composition; at the same time, it also has the better dispersion and smaller particle size, and thus has a higher hydrodesulfurization activity;
3. With a strong resistance to sulfur poisoning which makes it being a very potential liquid fuel hydrodesulfurization catalyst.
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Doped Tungsten Bronze Niobate Crystal Structure

Category: Tungsten Information
Published on 26 April 2016
The photorefractive performance and growth quality of Tungsten bronze (TB) niobate can be effectively improved by doping because of its special crystal structure. For example, potassium and sodium strontium barium niobate crystals doped with copper (Cu: KNSBN) has breakthrough on obtaining large crystal size and performance improvements. Doping modification in crystalline materials research has caught more and more attention. Therefore, studies on the mechanism of doping, the relationship of doping and crystals molecular design and changes of the compositions are necessary.
 
There are five types of structure position (Al, A2, C, Bl, B2)inside the TB niobate crystal structure, which provides favorable conditions for introducing other ions to doping modification. Common dopant ions are: monovalent cations Cu +, divalent cations Mg2 +, Ca2 + and Cu2 + etc., trivalent cation Cr3 +, Fe3 +, etc., tetravalent cations Zr4 +, Ti4 +, etc., and pentavalent cation Ta5 +, V5 + and hexavalent cation W6 +, etc. .
 
Dopant ions in crystal have the following functions. First, to make crystal growth streak reduced and crystal not easy to crack, so that large size crystalline material is easily to grow. Second, to make the crystal has good polarization performance, and the depolarization phenomenon is not easy to appear. In addition, the dopant ions into the crystal also have the following effects on crystal : (a) Changes of lattice constant. (b) Distortion of crystal symmetry. (c) effects on crystals phase transformation. At the same time, the amount of dopant ions into TB niobate crystal will lead to changes in other cations in the crystal more or less. Dopant ions get into the crystal structure of different positions due to its own characteristics and types of cations in crystal and occupying circumstances. So in the synthesis of crystal material, doping can improve the quality of the crystal growth and the performance of the crystal.

tungsten bronze structure
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Steel Bonded Carbide Description (2/2)

Category: Tungsten Information
Published on 26 April 2016

Steel bonded carbide has many advantages, compared with conventional steel, it has higher hardness, wear resistance, hardenability (the ability to obtain the hardened layer depth of quenching); compared with tungsten carbide, it has excellent machinability (such as turning, milling, planing, etc.,), heat treatable and weldable. It also by forging changes its dimensions and internal organizational structure to improve performance, which is generally not available in tungsten carbide. By electrical welding, insert welding, surfacing, vacuum welding, steel bonded carbide can meet a variety of application needs.

Steel bonded carbide also has a smaller proportion of high specific strength, good self-lubricating, high natural frequency and damping characteristics, a significant damping effect. Wherein the circular SiC grains is working with the workpiece surface forms rolling friction, so as to effectively avoid the adhesion of wear and abrasion wear. Combined with the advantages of steel and tungsten carbide, steel bonded carbide has a wide scope of application, which can be used in military materials, marine, aerospace materials, high temperature and corrosion-resistant parts, wear parts of damping, mold material, crushing mining tools, measuring instruments and some fields has special requirements of materials proportion and overall performance.

The machining principle of steel bonded carbide is low cutting rate, accurate control of cutting depth and length, do not add any coolant (except grinding process). If we violet these principles, the surface of steel bonded carbide will be hardened, which hiders the machining process. Material of the tool in the milling process usually uses the high-speed steel and carbide; drilling process should not add coolant to ensure that no oil and drill using medium voltage feed and promptly chip to prevent debris from wear and tear on the drill bit; grinding with high hardness, good self-sharpening diamond grinding wheel 120 #, but should pay attention to the amount of coolant; after quenching, steel bonded carbide will easily crack in the process of electrical machining. In order to prevent the cracks from appearing or extending, it should be extending the annealing time until the stress relief and using quenching or isothermal quenching process.

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