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  1. Home
  2. Tungsten Information

Tungsten Bronze and Avoid Hysteresis Driving Method

Category: Tungsten Information
Published on 18 April 2016
It is now the most widely used the multilayer piezoelectric actuators polarized by series of mechanical and electrical parallel. When adding constant pressure on the drive, the piezoelectric equation can be expressed as △L-Nd33V. N is the number of laminated ceramic; d33 is the piezoelectric constant; the V is the applied voltage; △L is the displacement generated in the thickness direction.
 
Figure following is the actual measured piezoelectric ceramic voltage - displacement curve of tungsten bronze series piezoelectric actuators under open-loop control. It can be seen that when the voltage begins to decrease from the maximum value, the displacement is not returned from the rising displacement curve , but there has been a large displacement hysteresis, particularly in the control voltage of 50V, the input voltage is the same as the corresponding displacement hysteresis has reached 0.231μm.
 
This hysteresis relationship between voltage and the displacement is the hysteresis characteristics of piezoelectric actuators. Which is because d can only be constant only when the material is a single crystal of single domain state and in a weak field. But for a piezoelectric ceramic material constituted by polycrystalline, because there are a lot of electricity domains on its composition crystal, when there is a strong electric field, steering motion of electricity domains make the d no longer a constant, but the with the function changing with electric field strength E. Thus, the amount of displacement generated by the driver is not only related to the voltage, but also to the changing piezoelectric constant. When the electricity domain is angle of 180 °, the drive will not produce displacement hysteresis when it is reversed; but when the electricity domain is angle of 90 °, when the voltage drops, 90 ° domain inversion will make the displacement of the drive in parallel or perpendicular in the direction of the electric field a non-linear increase, which will lead to voltage - displacement hysteresis of piezoelectric actuators.

hysteresis curve
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TiO2-Aluminosilicate Fiber Paper Composite Carrier Tungsten Trioxide Denitration Catalyst

Category: Tungsten Information
Published on 18 April 2016
aluminosilicate fiber paperCurrently, the most widely used SCR denitration catalyst is the vanadium pentoxide-tungsten trioxide-titanium dioxide base monolithic denitration catalyst, wherein the carrier is titanium oxide; the main active component is vanadium pentoxide; tungsten trioxide plays the roles of enhancing the acidity, expanding SCR denitration reaction temperature window, inhibiting anatase transfer into rutile, reducing the conversion of sulfur dioxide to sulfur trioxide, improving the ability of anti-poisoning of the catalyst.
 
In this paper, we will introduce the preparation of tungsten trioxide denitration catalyst which is taking titanium dioxide- aluminosilicate fiber paper as the composite carrier. The preparation steps are like bellows:
1. Select the silica-alumina fiber paper, industrial grade anatase type titanium oxide as raw material, the titanium dioxide slurry is first prepared (wherein 30% ammonia stabilized silica sol is added), then form to a cylindrical;
2. Dried at 100°C for 1 hour and calcined segment (respectively insulate at 100°C, 200 °C, 300°C, 500°C for 1 hour), to obtain a catalyst carrier;
3. Preparing the tungsten trioxide denitration catalyst by wet impregnation method, wherein the mass fractions of ammonium metavanadate, ammonium tungstate, ammonium molybdate are respectively 1% to 5%, 5% to 15% and 0% to 5%;
4. Drying the catalyst at 100°C for 1 hour and then segment calcined (respectively insulate at 100°C, 200 °C, 300°C, 500°C for 1 hour) to obtain tungsten trioxide SCR denitration catalyst.
 
Experiments have shown that the SCR denitration catalyst which takes titanium dioxide-aluminosilicate fiber paper as the composite carrier, the carrier and catalyst itself can maintain good porous structure in the condition of calcined at 500°C, while anatase titanium dioxide do not rutile; In addition, when the contents of active component-vanadium pentoxide, tungsten trioxide, molybdenum trioxide are respectively 3%, 7%, 4%, the denitration efficiency is up to 92%.
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Tungsten Trioxide Denitration Catalyst Alkali Metal Poisoning

Category: Tungsten Information
Published on 18 April 2016
flue gas denitration catalystTungsten trioxide denitration catalyst will be affected by a lot of dust in the flue gas and toxic substances during operation, and tends to be inactivated. Alkali metal poisoning is mainly due to the alkali metal can directly react with the active site, thus making the catalyst deactivation; the mechanism is that an alkali metal can react with the V-OH acid sites on the catalyst surface and generate V-OM, this will cause ammonia adsorption capacity of the catalyst dropped, thereby the activity of ammonia in the SCR denitration system reduced; moreover, the generated particles may also deposit on the surface of the catalyst or part holes, which will hinder the nitric oxide and ammonia spread to the inner of catalyst and finally cause catalyst deactivation. It is generally believed that alkali metal poisoning (Ca, Mg) is mainly physical poisoning, which the Ca and Mg may deposit on the surface of the catalyst pore to cause blocking, ammonia and NO contacting with the active catalyst sites obstructed, finally resulting in catalyst deactivation.
 
Experimental results have showed that:
1. Ca and Mg oxides affect catalyst activity
The NO conversion rate of tungsten trioxide catalyst is 95.84% at 300°C, the activity decreased obviously after Ca and Mg oxides added; when the molar ratios of Ca, Mg and V equals to 3.0, its activity respectively decreased to 82.0% and 71.24%.
2. Ca, Mg affect catalyst characterization
The incorporation of Ca and Mg oxides has not effect on vanadium pentoxide distributed on the carrier of tungsten trioxide denitration catalyst, that is to say vanadium pentoxide is still distributed in the state of no definite patterns or highly dispersed at the surface of the titanium dioxide. Furthermore, CaO and MgO also disperse in the amorphous or highly state at the catalyst surface and do not form the crystallization of CaO and MgO. With the increasing concentration of Ca and Mg, the amount of B Acid sites reduced, thus resulting in the weakened of ammonia adsorbing ability, the final running of SCR denitration impacted.
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Tungsten Electrode Production Technology-Sintering Process and Influence Factors

Category: Tungsten Information
Published on 18 April 2016

thorium tungsten electrodes

Tungsten powder and rare earth oxide powder after pressing, tungsten blanks’ density and strength have been greatly improved. After pressing, the blanks should to process sintering. The sintering process will affect tungsten blank’s density, grain size, distribution of rare earth oxides and high temperature evaporation loss quantity and so on, thereby affecting the performance of the tungsten electrode. In the sintering process, time, temperature, heating gradient, heating rate and purity are the main factors affecting the properties of sintered blanks.

When the powder particles is small, if the sintering temperature is too high, the tungsten grain will grow dramatically and will reduce the matrix diffusion coefficient of rare earth oxides in tungsten matrix, increasing electrode’s fare damage rate. Besides, high sintering temperature will lead to low-melting material aggregation, increasing segregation and rare earth oxides loss, so rare earth oxides distributed in the tungsten matrix is unevenly. Meanwhile, the sintering temperature is too high is prone to produce anti-sintering phenomenon, so that tungsten blanks density will decline. Because during the multi-component series sintering, the densification is based on diffusion, with the sintering temperature increase, the diffusion coefficient increases as well, and the shrinkage of sintered blanks become slow. When the sintering temperature is too low, the sintered density of the tungsten electrode can reach requirement also affect the using results.

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Tungsten Electrode Production Technology-Pressing and Sintering Process

Category: Tungsten Information
Published on 18 April 2016

tungsten electrodes

After using two-steps hydrogen reduction method reduced the tungsten powder and rare earth oxide powder, to process pressing. During pressing process uses steel mold pressing method. Tungsten powder and rare earth oxide affected by the pressing pressure, it will produce a series of displacement. Fine tungsten powder has smaller particles which can fill in the large grain tungsten powder, so tungsten powder particles to be re-arranged, resulting in doped tungsten powder volume greatly reduced. Besides, tungsten blanks density and strength are greatly enhanced. In addition, the tungsten powder particles under pressing pressure, the contact area between the particles is increase and the gap between the particles is reduce, increasing the cohesion between the powder particles, thereby improving the mechanical bite force between the powder particles, so the density and strength of tungsten blanks will be further improved. In the pressing process, the pressure is about 8.5Mpa.

Tungsten electrode is a refractory insoluble metal, so the sintering temperature is very high and usually uses self-resistive heating, namely, direct sintering method. During sintering, the sintering current is generally selected 90% fusing current, so this method is also called sintered sintering method. Sintering process will affect tungsten electrode’s density, grain size, rare earth oxides distribution and high temperature evaporation loss quantity and so on. And there are many factors affect sintering process, such as time, temperature, heating gradient, heating rate, powder purity. To well control these factors can obtain good performance sintered tungsten blanks, to produce good performance tungsten electrode.

Sintered tungsten blanks performance testing, we can observe the blanks surface color and surface defects, and you can also test blanks absorbent. Besides, you can also use drainage method to measure blank’s density. 

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Tungsten Carbide Slotting Cutter (2/2)

Category: Tungsten Information
Published on 18 April 2016

Generally used for machining hardened tungsten carbide slotting cutters were tested negative rake angle form the top edge so that both sides of the cutting edge blade angle to obtain the corresponding negative, slotting process will have beveled cutting characteristics. By increasing the negative rake angle cutting method to improve depth profile shaper cutters nose and the side edge chipping capacity and wear resistance. And this feature is not only suitable for cutting hardened hobbing, but also for slotting process. In order to maintain tungsten carbide slotting cutter based on the accuracy of the tooth to improve the cutting performance, the former top general use -5 ° blade angle is appropriate.

The flank of tungsten carbide slotting cutter is helicoid, which only in its truncated plane will have involute. However, when tungsten carbide slotting cutter made front corner and rear corner, the cutting edge will deviate from the cut surface, the shape with the theoretical involute is there are some errors, and this error is difficult to measure directly. So this will be difficult in the grinding process, the shape of the cutting edge will be further amended, and the need for tungsten carbide slotting cutter pressure angle correction.

In addition, in order to break through the conventional configuration (cone) tungsten carbide slotting cutter easily to be chipped, slotting low accuracy, the researchers also tried a new configuration of tungsten carbide slotting cutter for profiled convex instead of the traditional cone and as a shaper cutter teeth rake. As a cross-section will make a substantial increase in the absolute value of negative rake angle; curved front flank and the lateral flank cross a certain line in both the conical surface of the corner, so that the side edge space curve to flatten in case of the distortion caused by difficult control of the shape of the curve in space of cutting edge and ensure the cutting performance and surface quality. Overall, shaped convex curved tungsten carbide slotting cutter effectively solve the contradiction between the traditional configuration exist in the configuration tool and precision, thereby increasing wear resistance and chipping capability resistance.

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Tungsten Carbide Slotting Cutter (1/2)

Category: Tungsten Information
Published on 18 April 2016

From the appearance, slotting cutter is like a gear or a rack, which is widely used in fabricating spur and helical cylindrical gear meshing inside and outside. Especially for Multi-gear, herringbone gears and gear with a shoulder and shaped workpieces can be made by the slotting cutter with special structure, such as cam, internal spline and so on. According to the appearance, slotting cutter can be specifically divided into disc-shaped, tubular, bowl-shaped and taper shank type, and every shape of slotting cutter will correspond to the workpiece with different shape.

Disk-shaped gear shaper cutters are mainly used inside and outside straight tooth meshing, helical and herringbone gears; Cylindrical gear shaper cutters can be used in the processing module and a relatively small external gear; Bowl-shaped slotting cutter for multi-linking internal and external engagement with shoulder machining spur gears, the clamping nut at work can be accommodated in the body shaper cutters, which does not interfere with the cutting process carried out; Taper shank shaper cutters are mainly used in the processing and spur gear meshing helical gears. At present, in the actual production, high-speed steel is the most used material in slotting cutter, but there here are many studies have shown that compared with carbide shaper cutters with better performance. Especially in the hardness, the strength and wear resistance, tungsten carbide slotting cutter has a great improvement.

tungsten carbide slotting cutter

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Tungsten Bronze PZT Actuator Hysteresis Characteristics

Category: Tungsten Information
Published on 15 April 2016
With the development of nano-measurement technology, studies on enable multiple degrees of freedom nanometer positioning fretting table have caught more and more attention. Micro-table driving elements selection and use have a direct impact on the ultimate performance. Currently, there are many kinds of small displacement driving elements used in practice. And piezoelectric actuators has become one of the most widely used driving element in micro-positioning control areas for its small size, light weight, low the driving voltage, high precision and displacement resolution, fast frequency response, no heat, no noise, large capacity and other characteristics.
 
However, the inherent nonlinear characteristics, hysteresis characteristics and creep properties of piezoelectric ceramic material, have greatly limited the further improvement of piezoelectric actuator positioning accuracy, wherein the hysteresis error has the maximum impact on the accuracy. Therefore, how to improve the piezoelectric actuator hysteresis characteristics has become the most important issue need to be resolved of our ultra-precise positioning. In this regard, experts and scholars at home and abroad have done a lot of research and put forward a series of theories and methods to improve its characteristics. The methods to reduced latency in the drive open loop or semi-closed loop control currently proposed are: (1) The charge control method; (2) Connecting in series of small capacitance at both ends of the piezoelectric ceramic ; (3) Preisach model; (4) Generalized Maxwell model; (5) Polynomial approximation model; (6) Making capacitors and resistors as bridge. These methods control mostly through the establishment of complex mathematical models.
 
In this study, a new kind of hard piezoelectric actuator with tungsten bronze structure was used. Compared to soft perovskite piezoelectric actuators, hysteresis characteristics and creep error of this driver are greatly improved, especially the performance is relatively stable on the aspect. According to the main reason of generating hysteresis in the deformation process in their domain structure and crystal structure, some scholars have proposed a new "anti-hysteresis" driving method. "Anti-hysteresis" driving method can greatly reduce the impact of driving piezoelectric ceramic actuator hysteresis error, which can be used in high precision open-loop control of the micro device of which the process does not require continuous positioning, which greatly improves the hysteresis characteristics of the piezoelectric ceramic drive.
 
EX System Charts
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A Brief Introduction of Tungsten Granule

Category: Tungsten Information
Published on 15 April 2016

Tungsten granule is a flux which is major applied to the high frequency infrared carbon and sulfur analyzer. Therefore, tungsten granule also known as tungsten flux or pure tungsten flux. After processing the tungsten metal into some tiny particles, tungsten flux can be produced. The purity of tungsten granule is very high, it can reach more than 99.95%. And the size of tungsten granule is 20-40 mesh. As a flux, tungsten granule has good fluxing effectiveness and a stability analysis. Tungsten granule has been widely applied to the electronic chemical industry.

The shape of tungsten granule is polyhedral particles with bright gray color. Tungsten granule is mainly made of above tungsten. Tungsten is easily oxidized into tungsten oxide which belongs to acidity element and benefits the release of carbon dioxide and sulfur dioxide. In 1781, tungsten is a kind of mineral which was found by the Swedish chemist and mineralogist named Clance Tate.

There exist very low impurity elements in tungsten granule. The carbon element is less than 0.0008%, the sulfur element is less than 0.0005%, and an oxygen element is less than 0.05%. Therefore, tungsten granule has a high purity. In the most cases, tungsten granule is packed 1000g a bottle. The weight would be different due to the different specifications.

With the rapid development of modern science and technology, according to the demand of the production process, tungsten granule is widely applied to metallurgy, welding, and other analytical testing process. Nowadays, tungsten flux is the most indispensable fluxing materials for Infrared analyzer or other analyzers to measure the content of carbon and sulfur. It would release about 195.8 kcal / mol of heat when it start to oxidized with oxygen under a temperature greater than 650 ℃. Therefore, it has a strong fluxing effectiveness.

tungsten granule

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Applications of Tungsten Granule

Category: Tungsten Information
Published on 15 April 2016

The main application of tungsten granule is to analyze the Infrared carbon and sulfur oxide. The tungsten granule can also be applied to analyze the content of the carbon and sulfur of iron or metal. As a flux, the characteristic of tungsten granule is stability, and it can also reduce the melting point of comburent or promote the release of carbon and sulfur.

Tungsten particles can also be used as an additive in Infrared carbon and sulfur analyzer. The characteristic of Infrared carbon and sulfur analyzer is a high instantaneous heating, besides, the speed of its reaction is fast. Tungsten granule not only acts as a flux, but also adjusts the PH (potential of hydrogen) of the medium. In addition, the tungsten granule also has many other effects, such as stirring and anti-jamming. The tungsten granule of Infrared carbon and sulfur analyzer can make the values of carbon and sulfur more accuracy, so most Infrared carbon and sulfur analyzer consider tungsten granule as an additive.

With the rapid development of tungsten industry, tungsten granule industry has been widely applied in many fields. However, there are still many problems in applications of tungsten granule. For example, the utilization of tungsten granule resources is lower, and the irrational exploitation of tungsten would cause the ecological environment pollution. To solve these problems, enterprises should improve the recycling of tungsten granule.

tungsten granule

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