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  1. Home
  2. Tungsten Information

Processing of Ammonium Paratungstate from Tungsten Ores

Category: Tungsten Information
Published on 25 November 2015
To obtain highly purified, lamp grade ammonium paratungstate crystals from any of several different tungsten ores, the ore is reduced to finely divided status and slurried in heated HCl solution to convert tungsten values to WO.HO. Recovered tungstic oxide is washed and dissolved in heated aqueous solution of sodium carbonate or sodium hydroxide with the pH maintained at about 8 to 8.5 to form soluble sodium tungstate. Sodium hydroxide is added to raise the pH to about 10.5 to 11.5, and magnesium chloride is added in amount sufficient to somewhat neutralize the solution. Sodium hydroxide is added to raise the pH to about 10.5 to 11.5 to precipitate as hydroxide the magnesium and additional metallic impurities. At least one of ammonium sulfide and thioacetamide is and the heated solution is acidified to a pH in the range from about 2 to 3 to precipitate any molybdenum as MoS. The tungstate solution is then contacted with an organic, water-immiscible ion exchange liquid in which the active ingredient is an amine salt to extract the tungsten values. Tungsten values are then stripped from the ion exchange liquid with ammonium hydroxide to form ammonium tungstate solution, which in turn is separated. From the ammonium tungstate solution is crystallized highly purified ammonium paratungstate. The process is adaptable to continuous type operation.
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Structural Evolution of Ammonium Paratungstates during Thermal Decomposition

Category: Tungsten Information
Published on 25 November 2015
Mixed metal oxide systems (e.g. Mox(V,W)yO3-z) are employed for the partial oxidation of light alkenes. Ammonium paratungstate (APT) and ammonium heptamolybdate (AHM) are used as precursors for the production of WO3 and MoO3, respectively. The catalytic activity of these materials may depend on the treatment of the precursors. Therefore, studies of the decomposition process in order to identify and quantify tungsten oxide phases and their formation under various atmospheres, reveal correlation between catalytic activity and structural evolution of APT is very important. Here, we present results obtained from bulk structural studies on the thermal decomposition of APT in various reducing and oxidizing atmospheres. In this work the decomposition of APT is studied in situ by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). Using these two complementary methods allows us to follow the evolution of the short-range and long-range structure of the phases formed during the decomposition of APT, to elucidate the evolution of the primary and secondary structure under different conditions. 

 

Experimental 

Ammonium paratungstate (APT), (NH4)10H2W12O42*4H2O (OSRAM) was used as purchased. Transmission X-ray absorption spectra were measured in situ with the sample pellet in a flow reactor (4 ml total volume) under a controlled reactant atmosphere. In situ XAS experiments were performed at the W LIII edge (10.204 keV) (Hamburger Synchrotron Radiation Laboratory, HASYLAB, beamline X1), using a Si (311) double crystal monochromator. Temperature programmed decomposition was carried out at temperatures between 300 and 773 K in atmospheres of pure helium, 5 % hydrogen in helium, 20 % oxygen in helium, 10 % propene in helium, and 10 % propene/10% oxygen in helium. For the in situ XAS measurements APT was mixed with boron nitride and pressed into 5 mm in diameter pellets. Analysis of the gas phase was carried out with a quadrupol mass spectrometer, QMS 200 (Pfeifer), with a time resolution of ~ 2 s. Further details about the experimental XAS set-up used can be found in .

 

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Sintering Process Effect on Tungsten Copper Electrode Properties VI

Category: Tungsten Information
Published on 24 November 2015

The effect of sintering temperature on the electrical conductivity of tungsten copper electrode as shown below. We can learn from the figure, tungsten copper electrode conductivity with increasing sintering temperature increases at the beginning. When the sintering temperature is increased from 1150 ℃ to 1300 ℃, tungsten copper alloy electrode conductivity increased from 33.12% IACS to 41.23% IACS. However, when the sintering temperature increased from 1300 ℃ to 1450 ℃, the conductivity of tungsten copper electrodes decreased at this time.

This is due to the beginning of the sintering temperature increases, tungsten skeleton compacts and prepared better pore connectivity, obturator correspondingly less, tungsten, copper infiltrated distributed more evenly, so the conductivity rises with the rising sintering temperature. However, when the sintering temperature continues to rise, tungsten skeleton obturator also increases, thus affecting subsequent infiltration effect, making infiltration insufficient porosity increases, resulting in decreased conductivity of tungsten copper electrodes.

tungsten copper electrode












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Sintering Process Effect on Tungsten Copper Electrode Properties V

Category: Tungsten Information
Published on 24 November 2015

From the aspects of sintering kinetics, the sintered tungsten copper alloy electrodes tungsten powder mainly diffusion and flow of two different mechanisms. Especially in the media and high temperature sintering, surface diffusion becomes very obvious. At this time due to the fine-grained powder, which powder is larger than the surface area of the active surface of the large number of atoms, the diffusion surface it is relatively easy to carry out, which also makes sintered tungsten skeleton easily enter the third stage from the second stage.

If we can control the sintering in the second stage, the properties of tungsten copper electrode will be relatively ideal. The effect of sintering temperature on the hardness of tungsten copper electrode as follow:

tungsten copper electrode












The graph shows that it is similar to the effect on the density of tungsten copper, which increases in the beginning and stabilize gradually by the increasing temperature.

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Tungsten Carbide Forstner BitsⅡ

Category: Tungsten Information
Published on 24 November 2015

In last part we know that tungsten carbide Forstner bits are for drilling deep and precise smooth-sided holes through in wood working and come in sizes from 8–50 mm (0.3–2.0 in) diameter. Here we simply explain the basic structure of the bits.

The tungsten carbide Forstner bit includes a center point which guides it throughout the cut (and incidentally spoils the otherwise flat bottom of the hole). The cylindrical cutter around the perimeter shears the wood fibers at the edge of the bore, and also helps guide the bit into the material more precisely. Some of the bits have a total of two cutting edges in this cylinder. Forstner bits have radial cutting edges to plane off the material at the bottom of the hole. Some of the bits have two radial edges. Other designs may have more. Forstner bits have no mechanism to clear chips from the hole, and therefore must be pulled out periodically.

Sawtooth bits are also available, which include many more cutting edges to the cylinder. These cut faster, but produce a more ragged hole. They have advantages over Forstner bits when boring into end grain.

tungsten carbide forstner bit

(To be continued. This article is divided into several parts. Here is part 2. For part 1 please refer to  http://news.chinatungsten.com/en/tungsten-information/80700-ti-10454)

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Tungsten Carbide Forstner BitsⅠ

Category: Tungsten Information
Published on 24 November 2015

Forstner bits are named for Benjamin Forstner, a 19th century American gunsmith who is credited with inventing them. Gunsmiths were the first to popularize the bit; they prized it for its ability to bore a smooth-sided hole in woodwork.

Tungsten carbide Forstner bits are a cylindrical drill bit used to bore precisely flat, deep holes into wood. It is particularly popular in furniture making and other large-scale woodworking projects in part because of its ability to drill deeply and precisely, even against the grain or through various inlays and joined pieces. They can cut on the edge of a block of wood, and can cut overlapping holes. Because of the flat bottom to the hole, they are useful for drilling through veneer already glued to add an inlay. They require great force to push them into the material, so are normally used in drill presses or lathes rather than in portable drills. Unlike most other types of drill bits, they are not practical to use as hand tools.

Forstner bits typically come in a range of different diameters, they are commonly available in sizes from 8–50 mm (0.3–2.0 in) diameter. Sawtooth bits are available up to 100 mm (4 in) diameter.

tungsten carbide forstner bit

(To be continued. This article is divided into several parts. Here is part 1. For part 2 please refer to http://news.chinatungsten.com/en/tungsten-information/80701-ti-10455)

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Wear of Coated Tungsten Carbide Tool In Cutting H.S. Steel Ⅻ

Category: Tungsten Information
Published on 24 November 2015

In last part we get conclusions that the wear progress of tungsten carbide tool with (Al,Cr)N coating film is slower than the (Ti,Al)N coated one for the former one has higher hardness and higher oxidation temperature. And this part we go on to other conclusions based on the above experiments and analysis.

3) In addition, because the cutting temperature becomes lower due to the lower coefficient of friction of the (Al,Cr)N coating film, the wear progress of the (Al,Cr)N coated cemented tungsten carbide tool became slower.

4) In cutting hardened sintered steel with a (Al,Cr)N coated cemented tungsten carbide tool,  there  was  little influence of the cutting speed on the tool wear within the range of the cutting speed from 0.50 m/s to 1.00 m/s.

As mentioned above, it was clear that the (Al,Cr)N coated cemented tungsten carbide tool is an effective tool material in cutting hardened sintered steel.

coated tungsten carbide tool

(The end-This article is divided into several parts. Here is part 12. For part 11 please refer to http://news.chinatungsten.com/en/tungsten-information/80698-ti-10452)

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Wear of Coated Tungsten Carbide Tool In Cutting H.S. Steel Ⅺ

Category: Tungsten Information
Published on 24 November 2015

In last part we know that the tool wear mechanism and cutting temperature of tungsten carbide tools in the cutting speed range from 0.50 m/s to 1.00 m/s are similar. And this part we come to get a final conclusion based on the above experiments and analysis.

4. Conclusion

In this study, to clarify the effectiveness of aluminum-chromium coating film for cutting hardened sintered steels, tool wear was experimentally investigated. The hardened sintered steel was   turned with an aluminum-chromium based coated tungsten carbide tool according to a physical vapor deposition (PVD) method. Moreover, the tool wear of the aluminum-chromium based coated item was compared with that of the (Ti,Al)N coated tools.

The main results obtained are as follows:
1) The wear progress of the (Al,Cr)N coated cemented tungsten carbide tool was slower than that of the (Ti,Al)N coated cemented tungsten carbide tool.
 
2) Because the (Al,Cr)N coating film exhibited both higher hardness and higher oxidation temperature, the wear progress of the (Al,Cr)N coated cemented carbide became slower.

coated tungsten carbide tool

(To be continued. This article is divided into several parts. Here is part 11. For part 10 please refer to http://news.chinatungsten.com/en/tungsten-information/80697-ti-10451; for part 12, please refer to http://news.chinatungsten.com/en/tungsten-information/80699-ti-10453)

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Wear of Coated Tungsten Carbide Tool In Cutting H.S. Steel Ⅹ

Category: Tungsten Information
Published on 24 November 2015

In last part we know that The flank wear progress of tungsten carbide tool with (Al,Cr)N coating changes little with cutting speed from 0.5 m/s to 1.0 m/s. And this part we explain further the similarity of tool wear mechanism between the cutting speed of 0.50 m/s and 1.00m/s.

Fig. 5 shows the tool wear in the case of a cutting speed of 0.50 m/s. Fig. 5 (a) and (b) shows the SEM observation and Fig. 5 (c) shows the EDS analysis. Fig. 5 (b) shows the details of A shown in Fig. 5 (a). Fig. 5 (c) shows the EDS analysis in the case of the oxygen (O) mapping on the cutting part shownin Fig. 5 (a).

First, as compared with the wear of the tungsten carbide tool in the cutting speed 1.00 m/s shown in Fig. 1 (b) and that of the cutting speed 0.50 m/s shown in Fig. 5 (a), the tool wear of the cutting speed 0.50 m/s shows the same characteristics as that of the cutting speed 1.00 m/s. Next, as compared with the worn surface of the cutting speed 1.00 m/s indicated by “B” shown in Fig. 3 (ii)(a) and that of the cutting speed of 0.50 m/s indicated by “B” shown in Fig.5 (b), many striae scratched by any hard material are remarkably found on the worn surface in the case of both the cutting speed 1.00 m/s and the 0.50 m/s. Therefore, the main tool wear mechanism of the cutting speed 1.00 m/s and the 0.50 m/s is considered to be abrasive wear.

Finally, as compared with the oxygen element on the worn surface of the cutting speed 1.00 m/s shown in Fig. 3 (ii)(b) and that of the 0.50 m/s shown in Fig. 5 (c), the oxygen mapping on the cutting part shown in the cutting speed 0.50 m/s shows the same characteristics as that of the cutting  speed 1.00  m/s. Therefore, the cutting speed is considered to have little influence on the cutting temperature within the range of the cutting speed from 0.50 m/s to 1.00 m/s.As mentioned above the cutting speed is considered to have little influence on the tool wear within the range of the cutting speed from 0.50 m/s to 1.00 m/s.

 

tungsten carbide surface analysis figure 5

 (To be continued. This article is divided into several parts. Here is part 10. For part 9 please refer to http://news.chinatungsten.com/en/tungsten-information/80632-ti-10439; for part 11, please refer to http://news.chinatungsten.com/en/tungsten-information/80698-ti-10452)

Tungsten Carbide Supplier: Chinatungsten Online tungsten-carbide.com.cn Tel.: 86 592 5129696; Fax: 86 592 5129797;Email:This email address is being protected from spambots. You need JavaScript enabled to view it.
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Process for the Manufacture of Ammonium Paratungstate

Category: Tungsten Information
Published on 24 November 2015
Process for the manufacture of ammonium tungstate ammonium paratungstate, ammonium metatungstate and hydrated tungsten trioxide

Ammonium tungstate, ammonium paratungstate, ammonium metatungstate or hydrated tungsten trioxide is produced by passing tungstate anions through an anion exchange membrane into an aqueous solution containing ammonium cations under the driving force of an electrical potential for a time sufficient to achieve a pH within the range in which the desired tungsten compound will form.
 
In accordance with the invention a method has been discovered for manufacturing ammonium tungstate, ammonium paratungstate, ammonium metatungstate and tungstic acid requiring only ammonium hydroxide or other source of ammonium cations and a tungstate anion source as raw materials. These tungsten compounds can be manufactured in accordance with the invention without the production of useless byproducts and without the use of strong mineral acids, solvent extraction or precipitation reactions.
 
These tungsten compounds can all be produced in good yield and relatively free from cation impurities by passing tungstate anions under the influence of an electrical potential through an anion exchange membrane into an aqueous electrolyte containing ammonium cations until the desired pH of the electrolyte is reached for formation of the desired tungsten compound.
 
In another aspect of the invention, ammonium metatungstate or tungstic acid may be produced from normally insoluble ammonium paratungstate by using ammonium paratungstate crystals as the source of tungsten anions.
 
In another aspect of the invention, the alkali metal hydroxide formed by the removal of tungstate ions from alkali metal tungstate solution may be recovered and used to form additional alkali metal tungstates from tungsten sources such as ore concentrates.
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