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  1. Home
  2. Tungsten Information

Boehmite Prepares WO3 Contained Hydrodesulfurization Catalyst

Category: Tungsten Information
Published on 05 May 2016
boehmiteBoehmite is the main raw material to produce aluminum oxide. γ-Al2O3 obtained by the calcination of boehmite as the carrier, and load nickel oxide and tungsten trioxide, add a additive-fluorine, thus to produce tungsten trioxide hydrodesulfurization catalyst with high activity. The different purities of boehmite have a certain degree of influence on the activity of the desulfurization catalyst.
 
Low-purity boehmite prepares WO3 hydrodesulfurization catalyst
1. Take aluminum hydroxide powder generated by aluminum sulfate- sodium aluminate method from boehmite with a purity of 35% by weight, add the extrusion aid and water, extruded strip of 1.2 mm in diameter, dry in an oven at 120 ℃for 4 hours and then roasted at 550 ℃ in a tube furnace under the air for 4 hours to obtain γ-Al2O3 (A);
2. Dissolve ammonium fluoride in deionized water, add the carrier which is cooled down to room temperature for impregnation for 4 hours at room temperature;
3. Separate and dry the wet fluorinated alumina bar in an oven at 120 ℃ for 4 hours, then heated at 500 ℃ in a tube furnace with dry air for 4 hours to obtain fluorinated alumina strip, removed and cooled down to room temperature;
4. Add fluorided alumina to the deionized water containing with ammonium metatungstate and nickel nitrate, and separate after dip at room temperature for 4 hours to obtain wet catalyst;
5. Dry the wet catalyst in an oven at 120 ℃ for 4 hours, and calcine under the air in a tube furnace at 500 ℃ for 4 hours to obtain the catalyst A.
 
High-purity boehmite prepares WO3 hydrodesulfurization catalyst
1. Take aluminum hydroxide powder (obtained from the hydrolysis of aluminum alkoxide) with the boehmite purity of 70% by weight, add extrusion aid and water, then squeeze to a strip with a diameter of 1.2 mm, dry in an oven at 120 ℃ for 4 hours, then calcine at 550 ℃ for 4 hours in a tube furnace accompanying with the air to give γ-Al2O3 (B);
2. γ-Al2O3 (B) for the preparation of the carrier catalyst B, the same preparing method of the low purity boehmite.
 
Analysis showed that the aluminum oxide generated from high-purity of boehmite has the larger amount of acid, while the boehmite prepared by calcination has a larger amount of strong acid; tungsten desulfurization catalyst B prepared by aluminum alkoxide hydrolysis of a high-purity oxide boehmite has a higher activity.
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Tungsten Carbide Button Distribution Optimization on Drills (2/2)

Category: Tungsten Information
Published on 05 May 2016

In the early 1980s, some researchers have proposed the distribution of the drill bit buttons should follow three guidelines: 1. each cutting button has equal rock breaking volume; 2. equal wear rate; 3. equal rock consumption. Meet these three criteria in order to ensure rock breaking energy evenly distributed on each cutting tooth, so as to obtain the best rock-breaking effect. Theoretically, the process of tungsten carbide buttons for rock breaking can be divided in to three steps: elastic deformation (when the force is released, the rock surface can restore the status), fatigue process (also known as pressure crushed stage, surface cracks do not disappear and fracture rock surface) and volume breaking (The formation of shear body, under increasing pressure formed pit crushing).

When the adjacent tungsten carbide buttons impact the rock at the same time, the overall crushing effect depends on the nature of the deformation of the cross-belt. Reasonable button spacing will produce elastic deformation energy to rupture and push the rocks out with the increasing load; if the spacing of two buttons is too narrow, it will make the compacting zone too close to increase the difficulty of the shear rock; if the spacing of two buttons is too wide, the rock in the middle part will not be cracked and form rock ridges. Viewed from the impact energy, for the drills fixed diameter, the less number of buttons, the more impact energy of each button endure and the rock crushing volume will also increase accordingly. However, if the number of button is too small, which over the stress fracture of a single button, tungsten carbide button will be broken.

Buttons distribution firstly depends on the shape of the bit end face, which includes flat-shaped, arc-shaped, protruding, concave shape, and so on. The most used are flat-shaped and arc-shaped. Generally, tungsten carbide drill bit with large diameter usually uses arc end face and the small diameter often uses the flat-shaped. In intermediate buttons distributed in the cross section perpendicular to the bit axis, while the button are located on the inclined face of the drill bit. The outermost edge of buttons not only has to be mechanical support, but also should withstand the crushing function so that it has a greater amount of consumption than the buttons middle. Furthermore, it has high speed of linear velocity and requires a larger diameter, wider distribution and excellent quality.

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Tungsten Carbide Button Distribution Optimization on Drills (1/2)

Category: Tungsten Information
Published on 05 May 2016

The main component of tungsten carbide button is the hard phase of WC and the binder phase of Co, which has high hardness, high strength, excellent wear resistance and corrosive resistance and perfect impact resistance. So it can be widely used in high-pressure DTH (drill-the-hole), oil drilling, tunneling, mining industry and civil architecture. Due to its excellent wear resistance and impact resistance, compared with other materials, and it has higher drilling speed and the life span of drills and bits will be extended so that it does not need to change buttons constantly, which improves the overall efficiency and reliefs the labor.

On the basis of ensuring the stable properties of tungsten carbide buttons, the quantity and the distribution of buttons on drills and bits are also the significant factor on drilling performance. The essence of .tungsten carbide button distribution optimization on drills is based on keeping the excellent drilling properties and has the least number of buttons and the best location. Practically, a reasonable distribution of tungsten carbide button is beneficial for reducing the consumption of rock drilling, improving the drilling rate and in case of the wear of cutting buttons early to ensure the best cutting performance. Take DTH drill as an example, the bottom center of the distribution by the number of buttons surrounded, and one of the lowest penetration rates determines the drill bit ROP (rate of penetration), and the lowest life expectancy button also determines the life of the drill bit.

tungsten carbide buttons

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Nonstoichiometric Compound Tungsten Bronze

Category: Tungsten Information
Published on 05 May 2016
In 1823, a kind of sodium and tungsten oxide NaxWO3 was synthesized, its color is gold that similar to bronze, and it has electrical conductivity, therefore it’s known as tungsten bronze. Subsequently, there have been new compound oxide bronze being discovered and studied. Most of the transition metal element may be formed into bronze, except tungsten bronze, molybdenum bronze, bronze vanadium, niobium, tantalum, bronze and bronze are common as well.
 
Due to historical reasons, sometimes the oxides of tungsten bronze are also referred as bronze in the literature, bronze oxide can be represented as the formula AxMOn. In AxMOn Formula, A is positively charged atoms, M is a transition metal, n can be either an integer or a non-integer. AxMOn has following characteristics in structure. (1) the M in MOn is usually octahedral, and it’s often covalently linked between M-O. The octahedra further connected to form a skeleton structure with polyhedral open pores; (2) AxMOn partial skeleton structure is similar with MOn; (3) A is constantly electropositivity atom, filling cavities in the skeleton; (4) With the filling of A, transition metal M appears allotropy divalent ions, that becomes mixed valence ion, thereby forming a nonstoichiometric compound.
 
Tungsten bronze AaxWO3 (0 <x <1) belongs to such nonstoichiometric compounds, it can be widely used in optical, electrical and chemical fields because of its rich physical properties, such as the electrically induced discoloration device, photochromic mechanism and humidity sensors, etc. There are many synthesis ways of it. High temperature solid state reaction method and molten salt electrolysis method is the common method of synthesizing tungsten bronze, and there are also chemical synthesis machinery, high pressure sintering, thermal degradation, microwave synthesis, aqueous reduction method for the synthesis of this materials, and it has recently been reported that tungsten bronze can also be obtained by gas permeation method.
 
tungsten bronze structure
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Tungsten Alloy Shielding For Sterilization Of Medical Devices

Category: Tungsten Information
Published on 04 May 2016

With the development and application of modern science and technology, radiation technology has gradually entered people's daily life and played a vital role in the power generation, industrial, medical and other aspects. Radiation sterilization is a successful example of radiation technology, which is mainly used for the disinfection of disposable medical supplies and medical instruments by using ionizing radiation to kill pathogenic microorganisms (including viruses) to eliminate their poison. The secret of radiation sterilization is the radioactive isotope Co-60. Co-60 is a radioactive isotope of cobalt element that can decay into Ni-60 through β decay while emitting high-energy, high speed electron and two beams of gamma rays. Radiation sterilization is the use of these gamma rays to irradiate bacteria and viruses hiding in the medical supplies and medical equipment, resulting in physiological dysfunction, making it cannot able to grow and develop, or even causing death. The medical instruments to be disinfect by using radiation are mainly blood, surgical instruments, artificial heart and lung, suture materials, injection equipment, transfusion equipment, catheters, bandages, dressings, birth control appliances.Tungsten Alloy Shielding For Sterilization Of Medical Devices

Gamma ray, also called gamma radiation, is extremely high-frequency electromagnetic radiation and therefore consists of high-energy photons. When the body is irradiated with gamma-rays, gamma rays can enter the human body and erode the organic molecules (such as proteins, nucleic acids and enzymes organic molecules which constitute living cells), disturbing the chemical process inside human body, and even leading to cell death. Thus, medical workers should take certain precautions during the process of radiation sterilization of medical devices. In addition to time protection (reduction of exposure time), distance protection (away from the radiation source as far as possible), putting a shielding between man and sources to weaken the intensity of the radiation is also a good protective measures. The radiation shielding generally used for shielding radiation is tungsten alloy radiation shielding.

Due to the radiation sterilization is widely used in disinfection of medical devices in recent years, thus tungsten alloy radiation shielding for sterilization of medical devices can be used to shield radiation produced during the process of radiation sterilization. According to relevant research, the shielding performance of a metal material increases with the increasing of its density, therefore tungsten alloy radiation shielding for sterilization of medical devices has great shielding effectiveness with the high density of tungsten alloy, so that can efficiently absorb and shield radiation produced by the process of sterilization of medical devices, to weaken the intensity of the radiation, and prevent medical personnel from being subjected to radiation damage.

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Alcohol and Tungsten Bronze Powder Photochromic Effect

Category: Tungsten Information
Published on 04 May 2016
Sodium tungstate as raw material, prepared bronze tungsten oxide powder by hydrothermal synthesis method. The color of the powder turns into blue from light blue after 310 nm ultraviolet light irradiation, the color of the film gets deeper gradually with the increasing exposure time. Figure 1 shows the reflection spectrum of the powder of which the surface adsorbing ethanol, propanol and butanol after the illumination of different times. Compared with photochromic properties of powder without absorbing alcohol, with the extension of irradiation time, the reflected intensity of curve gradually decreased, especially the changes of the absorption peaks around 1 050 nm are obvious.
 
But after the powder adsorbs different kinds of alcohols, the absorption peak shapes have changed, the reflecting intensity at high wavelength is greatly reduced, and significantly reaching saturation and absorption take less time than when there is no absorption of alcohol, generally reducing 10 min. This may due to the reducing properties of alcohol, so that the powder produced more W5+ ions. In the three alcohol adsorption environment, propanol adsorbed powder is the best in color changing, the second is butanol adsorbed powder, the ethanol adsorbed is poor, the reason of that may be propyl of alcohol has a strong ability to push electrons, so that the hydrogen is easy to be away on the alcohol, and the carbon chain is relatively short, will not hinder the contact of propanol O - H and the tungsten oxide surface.
 
Figure 2 is the reflection spectrum of powder surface adsorbed ethylene glycol and glycerol respectively after the illumination of different times. As can be seen, which is similar with the photochromic curve of the powder in monohydric alcohols environment, with the extension of irradiation time, the reflection intensity of the curve decreases. Compared with monohydric alcohols, phototropy of powder adsorbed glycerol photochromic, with the alcohol metadata increases, the time to reach the required saturable absorption is shorter, and reflection intensity further decreases, it may be that the metadata increasing provides more alcohol O - H to contact with the tungsten oxide surface, thereby generating more W5+.

reflection spectra
reflection spectra
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WO3 Contained Low-Temperature Coal Tar Hydrodesulfurization Catalyst

Category: Tungsten Information
Published on 04 May 2016
coal tar hydrodesulfurization catalystThe high price brought by the dwindling oil resources has provided an excellent opportunity for coal chemical industry. Coal tar hydrodesulfurization catalyst is facing several difficulties in this stage:
Firstly, the high oxygen content, the water produced in the deoxygenation process is not conducive to the catalyst activity, stability and strength;
Secondly, high content of gum and residual carbon which results in deactivation of the catalyst and reactor fouled;
Thirdly, high content of sulfur and nitrogen in coal tar; Fourthly, coal tar contains a lot of aromatic hydrocarbons which can’t be removed deeply, and therefore a suitable acidic of catalyst is required.
 
The low temperature coal tar hydrodesulfurization catalyst containing with tungsten trioxide which has the suitable acidic is prepared as follows:
1. Preparation of carrier: Uniformly mix the quasi-boehmite, bentonite, H3 molecular sieves and BF3, add the binder (5%~10% the weight of boehmite) and extrusion aid (2%~5% the total weight of the mixture), then distilled water is added, kneading 30~60min, molding to obtain a molded carrier; drying the carrier at 15~60°C for 4~6 hours, at 100°C for 8~I0 hours; raising the temperature to 450~650°C at the rate of 2~5°C/min to roast for 4~6 hours, then we obtain a finished carrier.
2. Preparation of catalyst: Add tungstate, nickel and molybdenum salts respectively into the distilled water, stir under the temperature of 15~60°C until the solid completely dissolved; followed by the addition of phosphoric acid of 3%~6% by weight percentage concentration with stirring continued for 0.5~1 hour to get the impregnating liquid, wherein the weight percent concentrations of tungstate, nickel and molybdenum salt are respectively 15%~20%, 16%~21%, and 10%~18%; the carrier is impregnated into the impregnating solution and taken out after 3~5 hours, dried at 15~60°C for 2~6 hours, at 100°C for 2~6 hours; raising the temperature to 450~550°C at the rate of 2~5°C/min to roast for 4~6 hours to obtain a low-temperature coal tar refined hydrodesulfurization catalyst which contains tungsten trioxide.
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Heavy Oil HDM Desulfurization Catalyst Containing WO3

Category: Tungsten Information
Published on 04 May 2016
HDM desulfurization catalystIt is generally believed that the presence of sulfur in the feedstock is contributing to HDM reaction, however the nitrogen will inhibit that; experiment proved that sulfur exist in the form of hydrogen sulfide promoting HDM reaction is much larger than that of organic sulfur, in particular the newborn has the greater role which partially offsets the suppressing effect of nitrogen. Thus, catalyst with both desulfurization and demetallization has a higher performance, and can be used in the hydroprocessing of feedstock with high nitrogen.
 
Tungsten trioxide is an important active component of the desulfurization catalyst. We describe a method for preparing heavy oil HDM desulfurization catalyst as following:
1. Select two different forms of aluminum-containing material, aluminum oxide after calcined and aluminum hydroxide dry powder, the aluminum hydroxide dry powder is mixed with the adjuvants or additives containing solution, then get the carrier which the main ingredient is aluminum oxide by molding and activation;
2. The catalyst carrier is carried out an impregnation according to the needed content of active metal components and additives, and then generates the heavy oil HDM desulfurization catalyst containing WO3 by drying and roasting. Wherein the active ingredient are tungsten trioxide (or molybdenum trioxide) and nickel oxide, cobalt oxide, tungsten trioxide takes 0.5%~5.0% of the total mass of the catalyst; additive is alkali metal or alkaline earth metal oxides, such as lithium, sodium, potassium, accounting 0.1~3.0% of the total catalyst mass. Additives and active ingredients can be impregnated simultaneously and also step by step impregnation. Drying and calcining conditions are usually as follows: drying at 100~130 ℃ for 2~6 hours, calcining at 400~650 ℃ for 1~6 hours.
 
The feature of the catalyst prepared in this way is that the additives distributing non-uniformly, expressed as more distributing in the strong acid portion at the surface, and less in the weak acid portion, thus to equilibrium reducing the surface acidity of catalyst.
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Tungsten Copper Liner Warm Flow Compaction (2/2)

Category: Tungsten Information
Published on 04 May 2016

The liner is the key component of perforation bombs and armor-piercing, whose performance directly affects the penetration depth and piercing armor-piercing shells and after the explosion. In the early days, it uses turning process to fabricate copper rods and iron rods to form the liner shape or press-molding process to copper plate and iron plate. But these process has lower productivity, low dimensional accuracy and less prone to clogging of the perforation. With the development of powder metallurgy, powder sintering gradually replaced the cover plate liner, the production process is simplified, and overall efficiency has been improved.

However, due to the cover wall is thinner, easily deformed during sintering, poor surface fineness, it needs some optimization. Warm flow compaction can form the large component with a complex shape or structure and uniform density distribution, which is beneficial for the further expansion of tungsten copper material applications. It combines the advantages of injection molding and warm compacting process, which improves the flowability of the mixed powder by the viscosity changing of the binder. There are some experiments shows that the density distribution of W-70Cu liner by warm flow compaction is more uniform and the penetration is more stable.

Overall, compared with the injection molding suitable for the smaller components, warm flow compaction is more suitable for the larger components with complex structure and shape. It has higher requirements on the granularity of raw material and is sensitive to the temperature changes and the amounts of binder. Low temperature may cause mixing powder flow properties deteriorated, so that the tungsten copper shaped charge density distribution can not be molded or uneven. High temperature may obviously separate the two phase (the mixed powder and the binder). The excessive amount of adhesive may cause infiltrated tungsten skeleton pore through the large, so that the density decreases and easily deformed. In addition, warm flow compaction combines the advantages of injection molding and warm compacting process, and it can effectively improve the density, the penetration depth and armor capability of tungsten copper liner, which is the ideal choice for tungsten copper liner manufacturing in the future.

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Thoriated Tungsten Electrode Introduction

Category: Tungsten Information
Published on 04 May 2016

Grinding
tungsten electrodesGrinding electrode will produce radioactive dust into atmosphere. So it is recommended during grinding should make up a dedicated grindstone and local dust extraction. Besides, a simple filter mask is necessary unless you contact with small number of electrodes (less than about 20 per year). On the other hand, if the grinding wheel is not fitted with a protective viewing screen, eye protection should be worn. What’s more, the air extract from the grindstone should be collection so that the particles are deposited into a substantial disposable bag and will not release to the atmosphere just in case of ingestion or inhalation by welders.

After finish welding process, the area round the grinding wheels should be cleaned daily with a vacuum cleaner to remove dust particles. Besides, welders should be encouraged to wash their hands or whole body.

Welding
Some hazardous substance of thoriated tungsten electrode does occur during welding but it is a very small amount and the corresponding level of radioactivity is extremely low. However, wearing mouth, nose and eye protection during welding would further reduce any risk of contamination, and make welders more safety.

Alternatives to thoriated tungsten electrode
Lanthanum, cerium, yttrium and zirconium oxides can all be used with tungsten to produce lanthanated, ceriated, zirconiated and yttriated tungsten electrodes. Compared with thoriated tungsten electrode, they are all marginally radioactive, so the risk is even lower than with thorium oxide, so no specific precautions are needed. At the present, especially in developed counties they prefer to use these electrodes to place thoriated tungsten electrode. Among these rare earth tungsten electrodes, ceriated or lanthanated tungstens electrode are acceptable alternatives to thoriated tungsten electrode, particularly with a DC current, while zirconiated tungsten is preferred for AC current welding. There are very minor differences in the arc voltages required for equal currents between the various alternatives. Consideration should be given to justifying the use of thoriated tungsten electrodes in preference to other suitable alternatives.

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