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  2. Tungsten Information

SCR Denitration Catalyst Active Ingredient—Tungsten Trioxide

Category: Tungsten Information
Published on 22 March 2016
The principle of SCR technology technique is adding reducing agent (ammonia or urea) in the flue gas; the reducing agent will react with nitrogen oxides (NOx) to produce harmless nitrogen and water under a certain conditions. In the absence of a catalyst, the denitration reaction will only occur in a very narrow temperature range (800-1200℃). However, the SCR technology is using a catalyst to reduce the activation energy, so that making the reaction can be performed at lower temperatures (320-400℃).
 
The most critical component in SCR system is the denitration catalyst, which typically cost 30%~50% of the total investment denitration unit. SCR denitration catalyst uses titanium dioxide as the carrier, metal oxide such as vanadium pentoxide and tungsten trioxide as the main active ingredient. Cellular, plate and corrugated are the three main structures of SCR catalyst, among them cellular and plate are mainstream products, but the cellular has the highest market share recently. The main active material of cellular SCR denitration catalyst is Ti-W-V, it formed of various materials and then dried, calcined.
 
Under the ideal conditions, SCR denitration catalyst could use for long-term, however, there are varieties of toxic factors affect the active ingredient in the actual operation. In the process SCR denitration catalyst being used, the activity of catalyst will decline because of the active ingredient grain growth or even sintering, namely thermal aging effect; at the same time a number of toxic substances will poison the catalyst, resulting in partial or total loss of activity; Moreover, some contaminants (such as oil, coke etc.) reduce the activity by accumulating on the surface or plugging honeycomb catalyst pores. The SCR catalyst lost activity can be reborn by cleaning, adding the active components vanadium pentoxide, tungsten trioxide and drying to respond the major activity.
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Sulfur Dioxide Affects Tungsten Trioxide SCR Denitration Catalyst Activity

Category: Tungsten Information
Published on 21 March 2016
China is energy consuming country which is taking coal as the primary energy. In the combustion process of coal, it will produce a large amount of sulfur oxides (SOx) and nitrogen oxides (NOx), where industrial and mining coal combustion NOx emissions account for a very large proportion, about 70%. SCR is not only the most widely used currently, but also the most mature technology for stationary sources denitration technology. Denitration catalyst takes the key part of SCR technology, which directly determines the denitration efficiency. This article will examine the SCR denitration catalyst containing tungsten trioxide affected by sulfur dioxide.
 
The raw materials of tungsten trioxide denitration catalyst include: ammonium metavanadate, hydrated ammonium tungstate, ammonium molybdate, oxalic acid, anatase titanium dioxide, forming agent and additives. 
 
Experimental part:
1. when the temperature is 350 ℃, inlet the sulfur dioxide, we observe that the denitration efficiency is falling and then raising, after a certain reaction time, the activity of WO3 denitration catalysts is little less than that without sulfur dioxide;
2. When the sulfur dioxide gas concentration reaches a certain value, the denitration catalyst activity was inhibited in a certain period of time, but with the reaction continues, the inhibition will be weaker and weaker, and will eventually return to the state of non-sulfur dioxide; when the concentration of sulfur dioxide reaches to 1000ppm, the inhibition will be more evident.
 
Therefore, we can see: weakly inhibits the sulfur dioxide has on catalyst activity; low sulfur dioxide concentration has little effect on catalyst, but high sulfur dioxide concentration will cause a greater inhibition. This shows that the SCR denitration catalyst containing tungsten trioxide has a strong anti-sulfur dioxide poisoning feature.
 
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Tungsten Trioxide Prepares Efficient Denitration Catalyst-- Dipping Method

Category: Tungsten Information
Published on 21 March 2016
Currently, the dipping method is widely used because of its sample equipment and easy to operate in the domestic production of loading aid WO3 and active ingredient V2O5. However, the distribution of active ingredient and adjuvants uniformly on the carrier TiO2 with this method, and forming a large number of aggregations of vanadium which is influencing the denitration activity by affect the strong interaction between carriers. This paper presents a method of improving the impregnation solution by adding additives to improve the dispersion of vanadium and WO3, thus to increase the interaction between carriers, thereby improving the catalyst activity. 

schematics of SCR denitration
 
Steps are as follows:
1.Weigh the raw materials: weight the materials nano TiO2, WO3, ammonium metatungstate, vanadium ammonium oxalate solution, triethanolamine at a certain percentage;
2.Mixing the raw materials into deionized water, then adding TiO2 and stirring; wherein the oxalic acid concentration is l-2mol/L, and enough to dissolve ammonium metavanadate completely;
3.Drying at 70~120°C for 6 ~10 hours;
4.Calcinating the dried product in the air at 400-520°C for 3-6 hours;
5.Roasting in the original temperature in step 4 by introducing the reducing gas for 15-60 minutes, then removed the reducing gas, natural cooling down to obtain the efficient tungsten trioxide denitration catalyst. This step aims to adjust the firing atmosphere to further enhance the interaction between active ingredient and the carrier, thereby improving the denitration efficiency.
 
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Tungsten Bronzes

Category: Tungsten Information
Published on 21 March 2016
Tungsten bronze is a tungsten-containing nonstoichiometric compound, the outside looks like copper and has chemically inert. Tungsten bronzes is typically cubic crystal or tetragonal crystal. Insoluble in water and all acids except hydrofluoric acid, but soluble in an alkaline reagent. It can be used as a catalyst for oxidation of carbon monoxide and fuel cells getter.
 
A nonstoichiometric compound that empirical formula is MxWO3, and the M is typically an alkali metal, an alkaline earth metal, a rare earth metal ions, ammonium ions and so on. x is between 0 and 1. Tungsten bronzes typically have a metallic sheen and a special color. Species of M and change of the value x make it to have the properties of conductor or semiconductor. Crystal chemistry studies proved that tungsten bronze is essentially a solid solution formed after the alkali metal atoms inserted WO3 lattice. When all the vacancies are filled, the resulting compound is MWO3. The formation of tungsten bronzes is related to the tungsten’s variable atomic value, and if the space is only partially replaced by alkali metal atoms, some tungsten atoms will change from hexavalent to pentavalent.
 
Rare earth tungsten bronze M0.1WO3 is blue-violet powder, M is a rare earth element with a cubic crystal structure. Yttrium tungsten bronze YxWO3 has two structures of the tetragonal crystal and cubic crystal. Lithium and sodium, lithium and potassium may also form a mixed tungsten bronzes, such as NaxLiyWO3 and KxLiyWO3, where the x can be as small as 0.13, x + y can be up to 0.51. The former is usually a cubic crystal, the latter is hexagonal crystal.
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Cesium Tungsten Bronze Hydrothermal Synthesis

Category: Tungsten Information
Published on 21 March 2016
Cesium tungsten bronze (CsxWO3) is a kind of non-stoichiometric functional compound, with a specific structure of oxygen octahedral, having a low resistivity and low temperature superconducting properties. In recent years, it’s also found that CsxWO3 films have good near-infrared shielding performance, which is expected to replace the existing ITO conductive glass as a window material or that can be used as a good near-infrared heat insulation materials, having very attractive prospects in the automotive and construction sector. Currently the synthesis method of CsxWO3 is mostly confined to high-temperature thermal reduction, such as the vapor chemical transport method by Hussain, the hydrogen reduction method by Takeda, the solid-phase method by Leonova, such methods have shortcomings the high test equipment requirements and experimental process difficult to control.
 
As a simple and practical synthesis method, hydrothermal synthesis has been widely used in the tungsten bronze synthesis of Li, Na, K, etc., but the hydrothermal synthesis method for the synthesis of CsxWO3 has been reported in recent years. CsOH and WCl6 as raw materials, use solvothermal synthesis at a low temperature (200 ℃) for the first time , CsxWO3 powder is synthesized in ethanol solution. The research shows CsxWO3 films have good near-infrared shielding properties. CsOH and WCl6 are easily hydrolyzed and volatile, which is harmful to humans and the environment, therefore a more moderate material is used to synthesized CsxWO3 powder, which is necessary for achieving CsxWO3 powder scale production and practical application. Thus, cesium carbonate and sodium tungstate were used as raw materials in an experiment , citric acid as the reaction solvent, prepared CsxWO3 powder by hydrothermal synthesis, which studied the effects of the hydrothermal reaction time, the content of citric acid and ethanol on the synthesized CsxWO3 powder’s light absorption capacity, and to further explore the effect of UV irradiation on the near-infrared shielding performance of CsxWO3 film, analyzed the mechanism of absorption spectra and transmission spectra.

electron microscopic image
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Tungsten Oxide Inorganic Ceramic Film

Category: Tungsten Information
Published on 21 March 2016

Tungsten oxide inorganic ceramic film has high efficiency, high temperature resistance, high performance and stable chemical property. It has wide application field. Compared to organic film, it has following characteristics:

Tungsten oxide inorganic ceramic film

1.Tungsten oxide inorganic ceramic film has small pore size distribution which shows as normal distribution, 80% of them has error within ±10%. For example, the 0.05um film, among which 80% of pores are 0.049um-0.051um, it insures the stability of the applied film. This has a big difference from organic film which the pore size distributes uniformly.
2.Porosity of tungsten oxide can reach 35%-40% which ensures film flux.
3.Tungsten oxide inorganic ceramic film departure structure is more reasonable, there are supporting layer and separating layer, pore size is 5-10、1.0、0.6、0.2um, it becomes really gradient films which improve pollutant-resistance of film. The separating layer is even thinner which is easier to clean and wash. On the contrary, organic film is symmetric film, entry of film needs strict pre-treatment.
4.Tungsten oxide inorganic ceramic film has higher strength, it can resist pressure to 16bar, the supporting part can resist pressure to 30bar. It can ensure the dealing effects and stability in quality.
5.Tungsten oxide inorganic ceramic film has high insulating property.
6.Service life of tungsten oxide inorganic ceramic film is more than 5 years, however the organic film is only 3~6 months.
7.Chemical stability and thermal stability of tungsten oxide inorganic ceramic film is better than organic film, the strong acid, alkali and oxidizing agent can be used as detergent, steam sterilization can be applied directly. However, organic film can not be operated under the above mentioned conditions.

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Tungsten Copper Heat Sink Electrical Conductivity (2/2)

Category: Tungsten Information
Published on 21 March 2016

Under the intervention of external electric field, the outermost valence band electrons gain a little extra energy without violating the exclusion principle to reach many empty places within the band near. Compared with thermal excitation out-of-order, Excited electrons by the electric field and the field in the direction opposite to the momentum, it will produce a collective motion in the crystal, thereby forming current. For tungsten copper heat sink, due to different equivalent orbital and atom distance of W and Cu atoms, the band (or empty) overlap, constitutes a full conduction band, and has excellent electrical conductivity. For copper with divalent, its valence band is full band, which the valence band and a higher band overlaps, filled with electrons can occupy the vacated belt so that it has good conductivity; while tungsten with hexa-valence, its valence band is not full and the electrical conductivity is lower than copper phase. So this is a good proof of the conductivity of tungsten copper heat sink materials or conductivity depends on copper content.

The other influencing factor is porosity, which will hinder the movements of electrons. In other words, the higher porosity, the lower tungsten copper heat sink electrical conductivity. Due to tungsten copper is a kind of pseudo alloy, which composed of two kinds of metals with a big difference, there are a lot of interface and porosity between W and Cu grains. The experiment shows that tungsten copper composite material and its electrical conductivity were positively correlated with the density, the lower the density, the lower the conductivity. In addition, sintering temperature controlling is also important, electrical conductivity of tungsten copper has a sharp decline when it over-burnt. The main reasons comprise two, one is inside W phase has severe segregation and porosity, and as the main medium and Cu conductive phase may also undergone some degree of segregation, such that its penetration to the surface, the conductivity decreases with the decreasing content of Cu inside.

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Tungsten Copper Heat Sink Electrical Conductivity (1/2)

Category: Tungsten Information
Published on 21 March 2016

Except Rockwell hardness (HRB) of detection, it is essential that electrical conductivity measuring in tungsten copper composite materials as heat sink materials. Electrical conductivity is an important indicator to measure ability to conduct electricity of tungsten copper heat sink, which directly affects the final properties of products. The stronger ability to conduct electricity, the smaller electrical resistance, on the contrary, electrical resistance is greater. For hardness testing, if tungsten copper material over-burning, the inside Cu phase will exude and lead to the emergence of the hole, making the overall decrease in hardness; while the precipitation of Cu phase of segregation occurred, and thus will make the hardness not dropped significantly. Based on the theory, the relevant researchers have concluded that the most likely two factors tungsten copper electrical conductivity of heat sink, one is copper content, the other is the porosity.

Theoretically, tungsten copper composite material is composed of tungsten (W) and copper (Cu). W phase has higher hardness and melting point, lower electrical conductivity; on the contrary, Cu has lower hardness and melting point, but it has excellent electrical conductivity. Therefore, it can be speculate that electrical conductivity of tungsten copper heat sink material depends on how much copper content, the higher the copper content, the corresponding tungsten-copper composite conductivity is higher. From chemical energy band, different metal has different equivalent orbital and atom distance, which band (or empty) overlap, constitutes a full conduction band, and easily to have a metallic conductivity. So as long as there is not full of the conduction band, whether it itself is not full band, or the empty band and full band formed by overlapping unfilled band, under the action of external electric field will form a directional flow of electrons, thereby such that the material has conductivity.

tungsten copper heat sink materials

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Tungsten Gold-Plated Coin for Adult Ceremony

Category: Tungsten Information
Published on 21 March 2016
Whichever country has its special adult ceremony day. For parents, adult ceremony means that their children can have their own ability to live their own life; for teenagers, adult ceremony means that they are no longer the flowers in the greenhouse; they can find their own spaces and go their own ways with an independent personality. In China, the modern adult ceremony is a ceremony that held for the men and women who aged eighteen years or more. But whether it is China or other countries, in order to commemorate this special day of their children, most parents will send some meaningful gifts to their children in this day. 
 
The tungsten gold-plated coin, which engraved some profound meaningful words such as having a bright future, can be used as adult ceremony gifts to children in the adult ceremony. The blessing words and wished of this kind of tungsten gold-plated coin can be customized according to the custom’s needs. Tungsten gold-plated coin has the characters of non-toxic and environmental friendly; it is exquisite like gold, but has high cost-performance; it feels like real gold, but has higher wear resistance and abrasion resistance. Thus, it is a good choice for the parents to use as gifts to their children in the adult ceremony. Tungsten gold-plated coin for adult ceremony can not only plate gold, but also the silver, rose gold, copper and platinum etc., and its size, weight, and carving patterns also can be customized according to your special requirements.
tungsten gold-plated coin for adult ceremony
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Tungsten Gold-Plated Bar for Christmas

Category: Tungsten Information
Published on 21 March 2016
Christmas Day is the day for the Westerners to commemorate the birth of Jesus, it is one of the most important days for them, and became more and more popular in the world nowadays. During Christmas time, people will give each other Christmas cards, Christmas gifts, or the friends and families will wear Christmas hats, dress up the Christmas tree in order to share the joy of the year with each other. Red, white and green are the main colors for westerners in Christmas; they need to use these three colors to decorate their house as well as to celebrate the birthday of Jesus.
 
Tungsten gold-plated bar for Christmas is mainly to engrave the Santa Claus, deer, elk, Christmas tree or the text like “Merry Christmas” on its surface as a gift or souvenir. The purpose is to commemorate the good things of past year and the blessing and hope for the coming year. The weight of the tungsten gold-plated bar usually can be customized as required; the gold content also can be 18K, 22K, and 24K and so on for customers’ special requirements. Although tungsten gold-plated bar do not have the same hedging value as gold bar, but from the view of collection value, appreciation value and practicability, tungsten gold-plated bar can be longer preserved than gold bar; and in the same exquisite appearance, tungsten gold-plated bar would cost lower. Because of its beautiful appearance, people could not tear himself away from the tungsten gold-plated bar, but it is also has another kind of beauty without plating. The size, weight, carving pattern and word of tungsten gold-plated bar for Christmas can be customized as needed. 
tungsten gold-plated bar for Christmas
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